含聚合物佐剂的农药组合物 Pesticide-containing polymer adjuvant composition

[0001] 发明背景发明领域 [0001] BACKGROUND OF THE INVENTION Field of the Invention

[0002] 本发明广泛涉及农药组合物和方法，其中所述组合物包括各种农药，尤其是杀虫剂和除草剂和其混合物，和一定量的用于显著提高所述农药的有效性的共聚物佐剂或添加齐U。 [0002] The present invention broadly relates to pesticide compositions and methods, wherein said composition comprises a variety of pesticides, especially insecticides and herbicides, and mixtures thereof, and an amount to significantly improve the effectiveness of the pesticide copolymer adjuvant or add Qi U. 更具体地，本发明涉及含有相应量的马来酸和衣康酸组分的共聚物与选定的杀虫剂混合或使用的组合物和方法。 More particularly, the present invention relates to a copolymer containing the corresponding amounts of maleic acid and itaconic acid component of the compositions and methods of use of mixing or insecticide selected.

[0003] 现有技术说明 [0003] Prior Art

[0004] 农药，尤其是杀虫剂和除草剂的化学性质相异且众所周知。 [0004] The pesticides, especially insecticides and herbicides chemical properties distinct and well known. 过去已开发出大量此类农药，其中一些（如草甘膦）广谱而其他具有更特异的效用（如用于玉米的敌菌灵）。 In the past has developed a large number of these pesticides, some of which (such as glyphosate) while others have more specific broad-spectrum utility (such as for corn anilazine). 然而在所有情况中，人们努力使用最少的农药而获得相同或提高的有效性。 However, in all cases, efforts to use minimal pesticide while the same or improved effectiveness. 做这些是成本原因以及将农药使用对环境产生的影响减到最小。 The reason to do this is the cost and the environmental impact of pesticide use is minimized.

[0005] 过去已在农药配方上使用各类佐剂和添加剂。 [0005] in the past has been used on various types of adjuvants and additives in pesticide formulations. 这些包括PH调节剂、表面活性剂、 防泡剂、防蒸发剂、缓冲液、渗透剂、相容剂、消泡剂、沉淀剂、喷雾飘移控制剂、扩充剂、起泡齐ϋ、增湿剂、扩散剂、粘着剂、湿润剂和净水剂。 These include PH adjusting agents, surfactants, antifoaming agents, anti-evaporation agents, buffers, penetrating agents, compatibility agents, defoaming agents, precipitating agents, spray drift control agents, extenders, foaming homogeneous ϋ, moisturizers agents, dispersants, adhesion, wetting agents and purifying agent. 虽然这些方法或多或少地增加了农药性能， 但总体上它们对农药有效性没有提供显著的多重提高。 Although these methods are more or less increased pesticide properties, but in general they do not provide significant pesticide effectiveness multiple increase.

[0006] 因此本领域对能非常显著提高农药有效性、且其本身不引起过多的成本或环境影响问题的佐剂或添加剂类型仍存在真实且未能满足的需求。 [0006] Therefore, this field can be very significant for improving the effectiveness of pesticides, and it itself does not cause excessive costs or environmental impact of the type of adjuvant, or additive remains real and unmet needs.

发明内容 SUMMARY

[0007] 本发明克服了上述问题并提供含相应量的农药和共聚物的农药组合物，所述共聚物含各自含量的马来酸和衣康酸组分。 [0007] The present invention overcomes the above problems and to provide a pesticidal composition containing a pesticide and a corresponding amount of the copolymer, the copolymer of maleic acid and itaconic acid component containing respective content. 所述农药组分可为任何具有农药活性的试剂（如除草剂、杀虫剂、杀真菌剂和杀线虫剂）且优选选自杀虫剂、除草剂、及其混合物的组。 The pesticide component can be any agent having a pesticidal activity (such as herbicides, insecticides, fungicides and nematicides) and is preferably selected from insecticides, herbicides, and mixtures of. 公知的拟除虫菊酯和有机磷酸酯农药以及草甘膦除草剂适于用在本发明中。 The known pyrethroid and organophosphate pesticides and glyphosate herbicide suitable for use in the present invention.

[0008] 本发明优选的共聚物佐剂为含马来酸和衣康酸组分的共聚物，所述组分通常源自相应的酸或酸酐。 [0008] Preferred copolymers of the present invention is an adjuvant containing maleic acid and itaconic acid component of the copolymer, the components are generally derived from the corresponding acid or anhydride. 虽然其他单体也可用在所述马来酸-衣康酸共聚物中，但优选这些单体仅以极少含量存在，最多约7重量％，优选最多约4重量％。 While other monomers may also be used in the maleic acid - itaconic acid copolymer, it is preferred that these monomers only little amounts, up to about 7% by weight, preferably up to about 4% by weight. 反过来说，所述共聚物应含至少约93重量％、优选至少约96重量％的衣康酸和马来酸单体。 Conversely, the copolymer should contain at least about 93% by weight, preferably at least about 96 weight percent of itaconic acid and maleic acid monomers. 最优选地，所述共聚物主要或全部由马来酸和衣康酸组分组成。 Most preferably, the copolymer is composed primarily or exclusively from maleic acid and itaconic acid component. 此外，虽然其他聚合物或共聚物可形成本发明组合物的部分，在优选方面，所述衣康酸/马来酸共聚物在所述组合物中是优势聚合物组分。 Moreover, although other polymers or copolymers of the composition of the present invention may be formed, in a preferred aspect, the itaconic acid / maleic acid copolymer is an advantage in the polymer component composition. 通常，所述组合物包括相应的农药部分和聚合物部分，以聚合物部分总重为100重量％计，所述聚合部分具有至少约60重量％ (更优选至少约80重量％，且最优选至少约90重量％ ) 的所述优选衣康酸/马来酸共聚物。 Typically, the composition comprises a respective portion of the pesticide and the polymer portion, the polymer portion of the total weight of 100 wt% of the polymeric portion having at least about 60 wt% (more preferably at least about 80 weight percent, and most preferably at least about 90% by weight) of the preferred itaconic acid / maleic acid copolymer. 最优选地，所述聚合物部分主要由所述衣康酸/马来酸共聚物组成，即其基本不含其他类型单体。 Most preferably, the polymer mainly composed of the itaconic acid / maleic acid copolymer, i.e. it is substantially free of other types of monomers.

[0009] 本发明的组合物基本可用于必须或需要农药性能的任何环境，如土壤或叶片应用的农业使用，或用在硬表面如室内或建筑物虫害控制同样，可用任何已知的方法将所述组合物作为液体或固体使用。 Hard surfaces such as interior or building pest control Similarly, any known methods [0009] The compositions of the invention can be used in substantially any environment or be required pesticide properties, such as soil or leaf application of agricultural use, or for use in the Use of the composition as a liquid or solid. 在农业应用中，所述组合物优选是适于播撒喷雾应用的水分散体或溶液。 In agricultural applications, the composition is preferably adapted to spread the spray application of an aqueous dispersion or solution. 通常，与等量的无本文共聚物佐剂或添加剂的农药相比，本发明组合物提供至少约2倍、更优选至少约3倍的更强的农药有效性。 Typically, compared to a copolymer the pesticide adjuvant herein or an equivalent amount of the additive-free composition of the present invention provide at least about 2-fold, more preferably greater effectiveness of the pesticide at least about 3-fold.

[0010] 优选实施方式的详述 [0010] Detailed Description of preferred embodiments

[0011] 本发明依据的发现是共聚物佐剂或添加剂可显著改善广谱农药的有效性。 [0011] found that in accordance with the present invention is a copolymer adjuvants or additives can significantly improve the effectiveness of a broad spectrum of pesticides. 最需要地，所述共聚物与所述农药混合以形成混合物，然后可将该混合物应用于土壤、在叶片应用中、在硬表面上、作为气雾剂、作为液体或固体组合物的添加剂（如肥料）、或在需要农药活性的任何其他环境中。 Most needed, said pesticide with the copolymer to form a mixture, the mixture may then be applied to the soil, in leaf application, on a hard surface, as an aerosol, liquid or solid composition as an additive ( such as fertilizers), or in any other environment in need pesticidal activity. 或者，所述农药和共聚物可同时或顺序（通常在彼此的对小时内） 应用于土壤。 Alternatively, the pesticide and copolymer may be simultaneously or sequentially (often within hours of each other) is applied to the soil. 在使用混合组合物的情形，该组合物通常为水分散剂或溶液的形式，一般含水、农药、和共聚物组分。 In the case of using the mixed composition, the composition is typically in the form of aqueous dispersions or solutions, generally aqueous, pesticides, and a copolymer composition. 其他少量成分也可用在组合物中，如表面活性剂和PH调节剂，或任何其他前述本领域已知的佐剂或添加剂。 Other minor components may also be used in the composition, such as surfactants and PH adjusting agent, or any other of the preceding or adjuvants known in the art additives.

[0012] 本发明的组合物中所用的农药广泛选自杀虫剂和除草剂。 [0012] The pesticidal composition in the present invention are selected from widely used pesticides and herbicides. 对于杀虫剂，尤其优选合成除虫菊酯和有机磷酸酯。 For insecticides, particularly preferred pyrethroid and organophosphate. 例如，扑灭司林（C21H20C1203，（3-苯氧基苯基）甲基3-(2，2-二氯乙烯基）-2，2_ 二甲基-环丙烷-1-羧酸酯，CAS#52645-53-l)和联苯菊酯(C23H22C1F302, (2-甲基-3-苯基苯基）甲基（1S，3S)-3_[ (Z)-2-氯-3，3，3-三氟丙-1-烯基]-2，2-二甲基环丙烷-1-羧酸酯丄45#82657-04-；3)为合适的除虫菊酯类。 For example, permethrin (C21H20C1203, (3- phenoxyphenyl) methyl 3- (2,2-dichloro-vinyl) -2,2_ dimethyl - cyclopropane-1-carboxylic acid ester, CAS # 52645-53-l) and bifenthrin (C23H22C1F302, (2- methyl-3-phenyl) methyl (1S, 3S) -3_ [(Z) -2- chloro-3,3,3 - trifluoro-propan-1-enyl] -2,2-dimethyl-cyclopropane-1-carboxylate Shang 45 # 82657-04-; 3) is suitable pyrethrins. 本发明所用的典型有机磷酸酯农药为马拉硫磷（C10H1906PS2，2-( 二甲氧硫膦基硫代）丁二酸二乙酯， CAS#121-75-5)。 Typical organophosphate pesticide in the present invention is malathion (C10H1906PS2,2- (dimethoxy-phosphinothioyl-ylthio) succinic acid diethyl ester, CAS # 121-75-5).

[0013] 更普遍地，本发明使用下述杀虫剂： [0013] More generally, the present invention using the following insecticides:

[0014] 抗生素杀虫剂：阿洛氨菌素、苏云金素 [0014] Antibiotics Pesticides: Arlo ammonia streptozotocin, thuringiensin

[0015] 大环内酯杀虫剂 [0015] macrolide pesticides

[0016] 阿弗寿菌素杀虫剂：阿巴美丁、多拉克丁、埃玛菌素、依立诺克丁、伊维菌素、司拉克丁 [0016] Alfred life streptozotocin pesticides: abamectin, doramectin, emamectin, eprinomectin, ivermectin, Lake Ding Division

[0017] 米尔倍霉素杀虫剂：勒皮克丁（1印imectin)、尔倍克丁（ilbemectin)、米尔倍霉素肟化物、莫昔克丁 [0017] milbemycin insecticides: Le Puy g of (a printed imectin), Seoul times Curtin (ilbemectin), milbemycin oxime compounds, moxidectin

[0018] 多杀菌素类杀虫剂：斯平托姆（spinetoram)、多杀菌素（spinosad) [0018] spinosad insecticide: Spinney Thom (spinetoram), spinosad (spinosad)

[0019] 含砷杀虫剂：砷酸钙、乙酰亚砷酸铜、砷酸铜、砷酸铅、砷酸钾、砷酸钠 [0019] pesticides containing arsenic: arsenic, calcium, copper acetyl arsenite, arsenate, copper, lead arsenate, arsenic, potassium, sodium arsenite

[0020] 植物性杀虫剂：安纳巴松、印苦楝子素、右旋烯、烟碱、除虫菊素（瓜菊酯（瓜菊酯I、瓜菊酯II)、茉莉菊酯I、茉莉菊酯II、除虫菊素I、除虫菊素II)、苦味液、鱼藤酮、鱼尼丁、 沙巴达子 [0020] botanical insecticide: Anna Parsons, azadirachtin Su, D-ene, nicotine, pyrethrin (Cinerin (Cinerin I, Cinerin II), jasmine permethrin I, jasmine Daisy ester II, pyrethrin I, pyrethrin II), Angostura, rotenone, fish Nitin, Saporta child

[0021] 氨基甲酸盐/酯杀虫剂：恶虫威、西维因 [0021] carbamate / ester insecticide: bendiocarb, carbaryl

[0022] 苯并呋喃基甲基氨基甲酸盐/酯杀虫剂：丙硫克百威、虫螨威、呋喃威、单甲基克Hil^ (decarbofuran) [0022] benzofuranyl methyl carbamate / ester insecticide: benfuracarb, carbofuran, furan Wei, a single A Kick Hil ^ (decarbofuran)

[0023] 二甲基氨基甲酸盐/酯杀虫剂：地麦威、敌蝇威、海驱威（hyquincarb)、抗蚜威 [0023] two methyl carbamate / ester insecticide: to Maiwei enemy flies Granville, Granville sea flooding (hyquincarb), pirimicarb

[0024] 氨基甲酸肟盐/酯杀虫剂：棉铃威、涕灭威、涕灭砜威、丁酮威（butocarboxim)、丁酮砜威（butoxycarboxim)、灭多威、戊腈威（nitrilacarb)、草氨酰、噻螨威、抗虫威、硫双卡、久效威 [0024] oxime carbamate salt / ester insecticide: Boll Wei, aldicarb, aldicarb sulfoxide Granville, Granville butanone (butocarboxim), methyl ethyl ketone sulfone Wei (butoxycarboxim), methomyl, pentanenitrile Wei (nitrilacarb) , oxamyl, thiophene carbofuran, insect Wei, sulfur dual cards, long effect Viagra

[0025] 苯基甲基氨基甲酸盐/酯杀虫剂：除害威、灭害威、丁苯氨酯、丁苯甲氨酯、氯灭杀威、地虫威、敌克鲁威、二氧威、EMPC、杀虫丹、二乙基苯酚甲基氨基甲酸酯、仲丁威、异丙威、灭虫威、速灭威、兹克威、蜱虱威、猛杀威、残杀威、混杀威、XMC、灭杀威 [0025] phenyl methyl carbamate / ester Pesticides: Pesticides Viagra, Viagra terminator, butadiene urethane, urethane Ding benzyl chloride kill Granville, Granville ground insect enemy Kelu Wei, Dioxacarb, EMPC, killing Dan, diethyl phenol methyl carbamate, Fenobucarb, isoprocarb, methiocarb, metolcarb, Zike Wei, Wei lice ticks, Promecarb, killing Viagra, Viagra mixed kill, XMC, kill Wei

[0026] 干燥剂杀虫剂：硼酸、硅藻土、硅凝胶 [0026] The desiccant insecticides: boric acid, diatomaceous earth, silica gel

[0027] 二酰胺杀虫剂：氯虫酰胺、氰虫酰胺（cyantraniliprole)、氟虫酰胺 [0027] diamide insecticides: chlorantraniliprole, Cyantraniliprole (cyantraniliprole), flubendiamide

[0028] 二硝基酚杀虫剂：消螨酚、硝丙酚、戊硝酚、DNOC [0028] dinitrophenol pesticides: eliminate mites phenol, nitric propofol, amyl nitrate phenol, DNOC

[0029] 氟杀虫剂：氟硅酸钡、冰晶石、氟化钠、氟硅酸钠、氟虫胺 [0029] fluoride pesticides: acid barium fluoride, cryolite, sodium fluoride, sodium fluoride, sulfluramid

[0030] 甲脒杀虫剂：阿米曲拉、杀虫脒、伐虫脒、伐派虫脒（formparanate) [0030] formamidine pesticides: Ami Triton, chlordimeform, acetamiprid cutting, cutting school acetamiprid (formparanate)

[0031] 熏蒸杀虫剂：丙烯腈、二硫化碳、四氯化碳、氯仿、氯化苦、对二氯苯、1，2_ 二氯丙烷、甲酸乙酯、二溴乙烯、二氯乙烷、乙烯氧化物、氰化氢、碘甲烷、溴甲烷、甲基氯仿、二氯甲烷、萘、膦、硫酰氟、四氯乙烷 [0031] Fumigation insecticides: acrylonitrile, carbon disulfide, carbon tetrachloride, chloroform, chloropicrin, para-dichlorobenzene, 1,2_-dichloropropane, ethyl formate, ethylene dibromide, ethylene dichloride, ethylene oxides, hydrogen cyanide, iodomethane, methyl bromide, methyl chloroform, methylene chloride, naphthalene, phosphine, sulfuryl fluoride, tetrachloroethane

[0032] 无机杀虫剂：硼砂、硼酸、多硫化钙、油酸铜、硅藻土、氯化亚汞、硫氰酸钾、硅胶、硫氰酸钠、参阅砷杀虫剂、参阅氟杀虫剂 [0032] Inorganic insecticides: borax, boric acid, calcium polysulfide, copper oleate, diatomaceous earth, mercurous chloride, potassium thiocyanate, silica gel, sodium thiocyanate, refer arsenic insecticides, refer to fluoro kill pesticides

[0033] 昆虫生长调节剂 [0033] insect growth regulator

[0034] 几丁质合成抑制剂：双三氟虫脲、稻虱净、定虫隆、灭蝇胺、除虫脲、氟螨脲、氟虫脲、氟铃脲、氯芬奴隆、氟酰脲、多氟脲、氟幼脲、伏虫隆、杀铃脲 [0034] chitin synthesis inhibitors: Bistrifluoroacetic worm urea, buprofezin, Chlorfluazuron, cyromazine, diflubenzuron, fluorine mites urea, flufenoxuron, hexaflumuron, Fennu Long chlorine, fluorine Ureides, multi-fluorouracil, fluorine diflubenzuron, teflubenzuron, triflumuron

[0035] 保幼激素模拟物：保幼醚（印ofenonane)、苯氧威、氢化保幼素（hydroprene)、丙诺保幼素（kinoprene)、烯虫酯、吡丙醚、烯虫硫酯 [0035] juvenile hormone mimics: Juvenile ether (India ofenonane), fenoxycarb, hydrogenated juvenile hormone (hydroprene), propylene promise juvenile hormone (kinoprene), methoprene, pyriproxyfen, methoprene thioester

[0036] 保幼激素：保幼激素I、保幼激素II、保幼激素III [0036] juvenile hormone: juvenile hormone I, juvenile hormone II, juvenile hormone III

[0037] 蜕皮激素激动剂：环虫酰胼、氯虫酰胼、甲氧虫酰胼、虫酰胼 [0037] molting hormone agonists: ring worm corpus acid, chlorine acid corpus insects, methoxyfenozide corpus, insects acid corpus

[0038] 蜕皮激素：a-蜕皮激素、脱皮甾酮 [0038] ecdysone: a- ecdysone, ecdysterone

[0039] 蜕皮抑制剂：苯虫醚 [0039] molting inhibitors: benzene, ether worm

[0040] 抗保幼激素：抗保幼激素I、抗保幼激素II、抗保幼激素III [0040] anti-juvenile hormone: anti-juvenile hormone I, anti-juvenile hormone II, anti-juvenile hormone III

[0041] 未归类昆虫生长调节剂：环虫腈（dicyclanil) [0041] Others insect growth regulator: Central Fipronil (dicyclanil)

[0042] 沙蚕毒素类似物杀虫剂：杀虫磺、巴丹、杀虫环、杀虫双 [0042] nereistoxin like pesticides: bensultap, Bataan, insecticidal ring, Bisultap

[0043] 烟碱类杀虫剂：氟虫酰胺 [0043] neonicotinoid insecticides: flubendiamide

[0044] 硝基胍杀虫剂：噻虫胺、呋虫胺、吡虫啉、噻虫嗪 [0044] nitroguanidine insecticides: clothianidin, dinotefuran, imidacloprid, thiamethoxam

[0045] 硝基亚甲基杀虫剂：烯啶虫胺、硝乙脲噻唑（nithiazine) [0045] nitromethylene Pesticides: Nitenpyram, urea nitrate B thiazole (nithiazine)

[0046] 吡啶甲胺杀虫剂：啶虫脒、吡虫啉、烯啶虫胺、噻虫啉 [0046] pyridylmethylamine Pesticides: acetamiprid, imidacloprid, nitenpyram, thiacloprid

[0047] 有机氯杀虫剂：溴代-DDT、毒杀芬、DDT (pp' -DDT)、乙基-DDD、HCH( γ-HCH、立氯化苯）、甲氧氯、五氯酚、TDE [0047] organochlorine pesticides: brominated -DDT, toxaphene, DDT (pp '-DDT), ethyl -DDD, HCH (γ-HCH, lindane), methoxychlor, pentachlorophenol , TDE

[0048] 环戊二烯杀虫剂：艾氏剂、溴杀烯、冰片丹、氯丹、十氯酮、狄氏剂、二羟丙茶碱(dilor)、硫丹（α -硫丹）、异狄氏剂、HE0D、七氯、HHDN、碳氯灵、异艾氏剂、氯戊环、灭蚁灵 [0048] cyclopentadiene pesticides: aldrin, bromine kill ene, borneol Dan, chlordane, chlordecone, dieldrin, diprophylline (dilor), endosulfan (α - endosulfan) , endrin, HE0D, heptachlor, HHDN, carbon chlorine spirit, different aldrin, chloropentyl ring, mirex

[0049] 有机磷杀虫剂 [0049] organophosphorus pesticides

[0050] 有机磷酸盐/酯杀虫剂：溴苯烯磷、毒虫畏、丁烯磷、敌敌畏、百治磷、甲基毒虫畏、 福司吡酯、庚烯磷、杀虫乙烯磷（methocrotophos)、速灭磷、久效磷、二溴磷、萘肽磷、磷胺、 丙虫磷、TEPP、杀虫畏 [0050] The organic phosphate / ester insecticide: bromobenzene ene phosphorus, chlorfenvinphos, butene phosphorus, dichlorvos, Dicrotophos, methyl chlorfenvinphos, forskolin topiramate, heptenophos, ethylene phosphorus insecticide (methocrotophos) , mevinphos, monocrotophos, naled, naphthalene peptide phosphorus, amine, propaphos, TEPP, tetrachlorvinphos

[0051] 有机硫代磷酸盐/酯杀虫剂：蔬果磷、丁苯硫磷、稻丰散 [0051] The organic thiophosphate / ester insecticide: salithion, SBR parathion, phenthoate

[0052] 脂肪族有机硫代磷酸盐/酯杀虫剂：家蝇磷、胺吸磷、硫线磷、氯氧磷、氯甲磷、田乐磷（田乐磷-0、田乐磷-S)、内吸磷（内吸磷-0、内吸磷-S)、甲基内吸磷（内吸磷-ο-甲基、内吸磷-S-甲基）、砜吸磷（demeton-s-methylsulphon)、乙拌磷、乙硫磷、灭线磷、IPSP、异丙磷、马拉硫磷、虫螨畏、亚砜磷、异亚砜磷、砜拌磷、甲拌磷、治螟磷、特丁硫磷、甲基乙拌磷 [0052] aliphatic organic thiophosphate / ester insecticide: housefly phosphorus, amine uptake, Cadusafos, phosphorus oxychloride, phosphorus chlorine A, Tian Yue phosphorus (P -0 Le Tian Tian Le phosphorus - S), the absorption of phosphorus uptake -0 (inside, demeton -S), phosphorus uptake uptake -ο- methyl (Nene methyl, methyl demeton -S-), oxydemeton (demeton -s-methylsulphon), Disulfoton, ethion, Ethoprophos, IPSP, isopropyl phosphorus, malathion, fear of insects and mites, sulfoxide phosphorus, phosphorus different sulfoxide, sulfone mixed with phosphorus, phorate, sulfotep, terbufos, methyl Disulfoton

[0053] 一脂肪酰胺有机硫代磷酸盐/酯杀虫剂：赛果、果虫磷、乐果、益果、安果、灭蚜磷、 氧乐果、发果、苏果、蚜灭多 [0053] an organic thiophosphate fatty acid amide / ester Pesticides: Results, fruit worm phosphorus, dimethoate, benefit fruit, fruit Ann, off aphid phosphorus, oxygen dimethoate, fat fruit, fruit Su, aphid methomyl

[0054]-有机硫代磷酸肟杀虫剂：氯辛硫磷、辛硫磷、甲基辛硫磷 [0054] - phosphorothioate oxime organic pesticides: chlorine phoxim, phoxim, methyl phoxim

[0055] 杂环有机硫代磷酸盐/酯杀虫布丨：甲基吡啶、蝇毒磷、畜虫磷、二恶磷、因毒磷、灭蚜松、茂果、伏杀硫磷、吡唑硫磷、哒嗪硫磷、畜宁磷（quinothion) [0055] heterocyclic organic thiophosphate / ester insecticide cloth Shu: methyl pyridine, coumaphos, livestock insects phosphorus, dioxin phosphorus, phosphorus due to poison, off pine aphid, Mao fruit, phosalone, topiramate azole parathion, parathion pyridazine, livestock rather phosphorus (quinothion)

[0056]—苯并硫吡喃有机硫代磷酸盐/酯杀虫剂：苯噻双硫磷（dithicrofos)、苯噻硫磷(thicrofos) [0056] - benzo pyran sulfur organic thiophosphate / ester insecticide: benzoth temephos (dithicrofos), benzoth parathion (thicrofos)

[0057]-苯并三嗪有机硫代磷酸盐/酯杀虫剂：乙基谷硫磷、甲基谷硫磷 [0057] - benzo-triazine organic thiophosphate / ester pesticides: azinphos-ethyl, azinphos-methyl

[0058]-异吲哚有机硫代磷酸盐/酯杀虫剂：氯亚磷、亚胺硫磷 [0058] - isoindole organic thiophosphate / ester insecticide: chlorine phosphorous, phosmet

[0059]—异曙唑有机硫代磷酸盐/酯杀虫剂：异_唑磷、丙硫卩恶唑磷（zolaprofos) [0059] - exclusive Shu azole organic thiophosphate / ester insecticides: different _ Triazophos, propylthiouracil Jie isoxathion (zolaprofos)

[0060]—吡唑嘧啶有机硫代磷酸盐/酯杀虫剂：灭虫吡啶（chlorprazophos)、定菌磷 [0060] - pyrazolopyrimidine organic thiophosphate / ester insecticide: pest pyridine (chlorprazophos), fixed bacteria phosphorus

[0061]-吡啶有机硫代磷酸盐/酯杀虫剂：毒死蜱、甲基毒死蜱 [0061] - pyridine organic thiophosphate / ester insecticides: chlorpyrifos, chlorpyrifos-methyl

[0062]-嘧啶有机硫代磷酸盐/酯杀虫剂：丁嘧硫磷、二嗪磷、乙嘧硫磷、丙嘧硫磷、乙基虫螨磷、甲基虫螨磷、乙酰嘧啶磷、嘧啶磷、丁基嘧啶磷 [0062] - pyrimidine organic thiophosphate / ester insecticide: Ding ethyl parathion, diazinon, parathion, ethyl acetate, propyl ethyl parathion, pirimiphos-ethyl, pirimiphos methyl, acetyl pirimiphos pyrimidine phosphorus, butyl pirimiphos

[0063]-喹喔啉有机硫代磷酸盐/酯杀虫剂：喹硫磷、甲基喹硫磷 [0063] - quinoxaline organic thiophosphate / ester insecticide: Quinalphos, methyl Quinalphos

[0064]—噻二唑有机硫代磷酸盐/酯杀虫剂：乙基杀扑磷、噻唑磷、杀扑磷、乙噻唑磷 [0064] - thiadiazole organic dithiophosphate / ester insecticide: ethyl methidathion, Fosthiazate, methidathion, B Fosthiazate

[0065]-三唑有机硫代磷酸盐/酯杀虫剂：氯唑磷、三唑磷 [0065] - triazole organic thiophosphate / ester insecticide: chlorazol phosphorus, triazophos

[0066] 苯基有机硫代磷酸盐/酯杀虫剂：偶氮磷、溴硫磷、乙基溴硫磷、三硫磷、虫螨磷、 杀螟腈、赛灭磷、异氯磷、除线磷、牛津郡丙硫磷（etaphos)、伐灭磷、皮蝇磷、杀螟硫磷、丰索磷、倍硫磷、乙基倍硫磷、速杀硫磷、碘硫磷、倍硫磷亚砜、对硫磷、甲基对硫磷、芬硫磷、对氯硫磷、丙溴磷、低毒硫磷、硫灭克磷、硫甲双磷、皮蝇磷-3、三氯丙氧磷 [0066] phenyl organic thiophosphate / ester insecticide: Even nitrogen and phosphorus, bromine parathion, parathion, ethyl bromide, three parathion, pirimiphos, cyanophos, race acephate, different chlorine phosphorus, In addition to the line of phosphorus, Oxfordshire propionate parathion (etaphos), cutting acephate, Hypoderma phosphorus, fenitrothion, fensulfothion, fenthion, ethyl fenthion, speed kill parathion, parathion iodine, times sulfoxide parathion, parathion, methyl parathion, parathion Finland, chlorine parathion, profenofos, low toxicity of parathion, aldicarb sulfur phosphorus, sulfur and phosphorus A double skin flies phosphorus -3, three chloropropionate Paraoxon

[0067] 膦酸盐/酯杀虫剂：布托酯、敌百虫 [0067] phosphonate / ester insecticide: Bhutto esters, trichlorfon

[0068] 硫代膦酸盐/酯杀虫剂：甲基灭蚜磷 [0068] dithiophosphonate / ester insecticide: Methyl off aphid phosphorus

[0069] 苯基乙基硫代膦酸盐/酯杀虫剂：地虫磷、壤虫磷 [0069] phenyl ethyl dithiophosphonate / ester insecticide: FONOFOS, phosphorus soil insects

[0070] 苯基苯基硫代膦酸盐/酯杀虫剂：苯腈磷、EPN、福赐松 [0070] phenyl dithiophosphonate / ester insecticide: Benzonitrile phosphorus, EPN, thanks to loose blessing

[0071] 氨基磷酸盐/酯杀虫剂：育畜磷、苯线磷、伐线丹、二噻磷、棉安磷、甲胺基嘧啶磷(pirimetaphos) [0071] amino phosphate / ester insecticide: educating livestock phosphorus, fenamiphos, cutting the line of Dan, two thiophene phosphorus, phosphorus Ann Cotton, pirimiphos methyl amine (pirimetaphos)

[0072] 硫代磷酰胺（phosphoramidothioate)杀虫剂：乙酰甲胺磷、水胺硫磷杀虫剂、异柳磷、甲基异柳磷、甲胺磷、烯虫磷 [0072] phosphoroamidothioate (phosphoramidothioate) pesticides: acephate, Isocarbophos pesticides, isofenphos, methyl isofenphos, methamidophos, methoprene phosphorus

[0073] 偶磷胼（phosphorodiamide)杀虫剂：甲氟磷、叠氮磷、丙胺氟、八甲磷 [0073] Even phosphorus corpus (phosphorodiamide) Pesticides: dimefox, stacked nitrogen and phosphorus, fluorine propylamine, schradan

[0074] 噃.二嗪杀虫剂：茚虫威 . [0074] Fan insecticide diazinon: indoxacarb

[0075] 嘴.二唑酮（oxadiazolone)杀虫剂：恶虫酮 [0075] mouth oxadiazolone (oxadiazolone) pesticides: metoxadiazone

[0076] 邻苯二甲酰亚胺杀虫剂：氯亚磷、亚胺硫磷、胺菊酯 [0076] phthalimide insecticides: chlorine phosphorous, phosmet, tetramethrin

[0077] 吡唑杀虫剂：氯虫酰胺、溴氰虫酰胺、敌蝇威、吡螨胺、唑虫酰胺 [0077] pyrazole insecticides: chlorantraniliprole, bromine Cyantraniliprole enemy flies Viagra, Tebufenpyrad, azole insect amide

[0078] 苯吡唑杀虫剂：乙酰虫腈（acetoprole)、乙虫腈、氟虫腈、吡唑硫磷(pyraclofos)、吡嗪氟虫腈（pyrafluprole)、吡啶氟虫腈（pyriprole)、甲烯氟虫腈(vaniliprole)[0079] 拟除虫菊酯类杀虫剂 [0078] phenyl pyrazole insecticides: acetyl fipronil (acetoprole), ethiprole, fipronil, pyrazole parathion (pyraclofos), pyrazine fipronil (pyrafluprole), pyridine fipronil (pyriprole), A ene fipronil (vaniliprole) [0079] pyrethroids

[0080] 拟除虫菊酯杀虫剂：氟酯菊酯、丙烯菊酯（生物丙烯菊酯）、熏虫菊、联苯菊酯、苄呋烯菊酯（bioethanomethrin)、环戊烯菊酯、乙氰菊酯、氟氯氰菊酯（0_氟氯氰菊酯）、格林奈（Y-格林奈、λ-格林奈）、氯氰菊酯（α-氯氰菊酯、β-氯氰菊酯、θ -氯氰菊酯、 ζ -氯氰菊酯）、苯醚氰菊酯、溴氰菊酯、四氟甲醚菊酯、苄菊酯、烯炔菊酯、芬氟司林、吡氯氰菊酯、甲氰菊酯、氰戊菊酯（顺式氰戊菊酯)、氟氰菊酯、氟胺氰菊酯（τ -氟胺氰菊酯)、 抗虫菊、炔醚菊酯、甲氧卞氟菊酯、氯菊酯（生物氯菊酯、反式氯菊酯)、苯氧司林、丙炔菊酯、丙氟菊酯（profluthrin)、苄氯菊脂、苄呋菊酯（生物苄呋菊酯、顺式苄呋菊酯）、七氟菊酯、甲烯菊酯（terallethrin)、胺菊酯、四溴菊酯、四氟菊酯 [0080] pyrethroid insecticides: acrinathrin, allethrin (Bioallethrin), smoked tetramethrin, bifenthrin, permethrin resmethrin ene (bioethanomethrin), cyclopentene permethrin, B cyhalothrin, cyfluthrin (0_ cyfluthrin), Gelin Nai (Y- Gelin Nai, λ- Gelin Nai), cypermethrin (α- cypermethrin, β- cypermethrin, θ - cypermethrin, ζ - cypermethrin), benzene, ether cyanide-ju esters, deltamethrin, permethrin tetrafluoroethylene ether, benzyl permethrin, empenthrin, fenfluramine Mr Lam, topiramate cypermethrin, fenpropathrin, fenvalerate (esfenvalerate), fluorine cyhalothrin, fluvalinate (τ - fluvalinate), insect chrysanthemum, acetylene phenothrin, permethrin methoxy Bian fluorine, permethrin (biological permethrin, trans permethrin) phenoxy Mr Lam, prallethrin, propyl fluoride permethrin (profluthrin), permethrin, resmethrin (bioresmethrin, cis-resmethrin), tefluthrin, methylene Permethrin (terallethrin), tetramethrin, tralomethrin, PTFE permethrin

[0081] 拟除虫菊醚杀虫剂：依芬普司、三氟醚菊酯、溴氟醚菊酯、普垂菊酯(protrifenbute)、氟娃菊酉旨 [0081] pyrethroid insecticides ether: according Fenpu Division, trifluoroacetic ethofenprox, bromine, fluorine phenothrin, permethrin Poor vertical (protrifenbute), fluorine baby daisy unitary purpose

[0082] 氨基嘧啶（pyrimidinamine)杀虫剂：嘧虫胺、嘧螨醚（pyrimidifen) [0082] aminopyrimidine (pyrimidinamine) Pesticides: ethyl amine insects, mites ethyl ether (pyrimidifen)

[0083] 吡咯杀虫剂：溴虫腈 [0083] pyrrole insecticide: Chlorfenapyr

[0084] 特特拉姆酸（tetramic acid)杀虫剂：螺虫乙酯 [0084] Tete Ram acid (tetramic acid) Pesticides: spirotetramate

[0085] 季酮酸杀虫剂：螺甲螨酯 [0085] season acid pesticides: spiromesifen

[0086] 噻唑杀虫剂：噻虫胺、噻虫嗪 [0086] thiazole Pesticides: clothianidin, thiamethoxam

[0087] 噻唑烷杀虫剂：噻螨威、噻虫啉 [0087] thiazolidinedione pesticides: carbofuran thiophene, thiacloprid

[0088] 硫脲杀虫剂：丁醚脲 [0088] thiourea Pesticides: diafenthiuron

[0089] 脲杀虫剂：伏康脲（flucofuron)、苏康脲（sulcofuron)、参见几丁质合成抑制剂 [0089] urea insecticides: V Kang urea (flucofuron), Su Kang urea (sulcofuron), see chitin synthesis inhibitors

[0090] 未归类杀虫剂：氯生太尔、环烷酸铜、克罗米酚、E)(D、抗螨唑、嘧酰虫胺(fenoxacrim)、氣虫义月宗(hydramethylnon)、稻;il；灵、特虫薄月青(malonoben)、ft 氣虫月宗(metaflumizone)、尼氟利地、蚊蝇灵、哒螨灵、啶虫丙醚、氟虫吡喹（pyrifluquinazon)、雷复尼特、氟啶虫胺腈（sulfoxaflor)、三苯噻螨吩（triarathene)、唑蚜威（triazamate)。 [0090] Others Pesticides: Blantyre triclosan, copper naphthenate, clomiphene, E) (D, azole anti-mite, insect acid ethyl amine (fenoxacrim), gas insects month were righteous (hydramethylnon) rice; il; spirit, especially insect thin blue moon (malonoben), ft gas worm month were (metaflumizone), niflumic Lee, the mosquitoes spirit, Pyridaben, Acetamiprid propyl ether, fipronil Bikui (pyrifluquinazon), Ray Bennett complex, amine fluoride Acetamiprid nitrile (sulfoxaflor), triphenyl thiophene mites thiophene (triarathene), azole pirimicarb (triazamate).

[0091] 上述杀虫剂和及其进一步的鉴定和描述的链接可参考http://WWW.alanW00d. net/pesticides/class_insecticides. html,其全文纳入本文。 [0091] link above insecticides and its further identification and description may refer to http: //WWW.alanW00d net / pesticides / class_insecticides html, incorporated herein in its entirety...

[0092] 特别优选的除草剂为草甘膦（C3H8N05P，[(膦酰基甲基）氨基]乙酸， CAS#1071-83-6)。 [0092] A particularly preferred herbicide is glyphosate (C3H8N05P, [(phosphonomethyl) amino] acetic acid, CAS # 1071-83-6). 本发明可用的其他除草剂包括： Other herbicide of the present invention can be used include:

[0093] 酰胺类除草剂：草毒死、氨唑草酮、氟丁酰草胺、胺酸杀、苄草胺、溴丁酰草胺、苯酮唑（cafenstrole)、⑶EA、三环塞草胺、二甲噻草胺（二甲噻草胺-ρ)、草乃敌、三唑磺、艾尼胺（etnipromid)、四唑草胺、氟唑磺隆、氟胺草唑、虎威、海罗胺（halosafen)、草特灵、异恶草胺（isoxaben)、敌草胺、抑草生、烯草胺、炔敌稗、醌萍胺、嘧啶肟草醚、特丙胺（tebutam) [0093] amide herbicides: grass poison, ammonia yl oxadiazon, fluorine butyrylcholinesterase alachlor, tryptophan kill, benzyl metolachlor, alachlor bromine butyrylcholinesterase, benzophenone azole (cafenstrole), ⑶EA, tricyclic grass plugs amine, dimethyl thiophene alachlor (dimethyl thiophene alachlor -ρ), grass is the enemy, triazole sulfonamide, Aini amine (etnipromid), tetrazole alachlor, flucarbazone, amine fluoride grass azole, Tiger, sea Luo amine (halosafen), grass Trane, isoxaben (isoxaben), Napropamide, naptalam, pethoxamide, alkyne propanil, Ping quinone amines, saflufenacil, special propylamine (tebutam)

[0094] 苯胺类除草剂：地快乐、落草胺、稗草胺、环草胺除草剂、吡氟草胺、乙氧苯草胺(etobenzanid)、芬纳胺(fenasulam)、氟噻草胺、三吡氟草胺（flufenican)、卤苯胺唑(ipfencartazone)、苯噻草胺、氟草磺、恶唑酰草胺、杀草利、萘丙胺、蔬草灭、氟吡酰草胺(picolinafen)、舌夂稗、甲磺草胺(sulfentrazone) [0094] aniline herbicides: to be happy, Luocao amines, barnyard grass amines, cyclic amines grass herbicides, diflufenican, ethoxy benzene metolachlor (etobenzanid), Fenner amine (fenasulam), flufenacet, three diflufenican (flufenican), halogen aniline azole (ipfencartazone), mefenacet, sulfur fluoride grass, oxazole acid alachlor, herbicide Lee, Naproanilide, vegetables grass off, flurbiprofen acid alachlor (picolinafen) , tongue Fan barnyardgrass, sulfentrazone (sulfentrazone)

[0095] 芳基丙氨酸类除草剂：新燕灵、草吡唑（草吡唑-M) [0095] aryl alanine herbicides: New Yan Ling, grass pyrazole (grass pyrazole -M)

[0096] 乙酰氯苯胺类除草剂：乙草胺、甲草胺、去草胺、丁烯草胺、异丁草胺、乙酰甲草胺、 二甲草胺、吡唑草胺（metazachlor)、甲氧毒草安（S-甲氧毒草安）、丙草胺、扑草胺、异丙草胺、广草胺、特丁草胺、甲氧噻草胺、二甲苯草胺（xylachlor)[0097] 磺酰苯胺（sulfonanilide)类除草剂：氟草黄、氯酯磺草胺(cloransulam)、双氯磺草胺、双氟磺草胺、唑嘧磺草胺、磺草唑胺、氟草磺胺、嘧磺草胺（pyrimisulfan)、氟唑草胺 [0096] acetyl chlorobenzene herbicides: acetochlor, alachlor, butamifos, butene alachlor, butachlor different, acetyl alachlor, dimethyl metolachlor, alachlor pyrazole (metazachlor), metolachlor (S- metolachlor), metolachlor, alachlor flutter, Propisochlor wide alachlor, butachlor especially methoxy thiophene alachlor, metolachlor xylene (xylachlor) [0097 ] anilide (sulfonanilide) herbicides: yellow grass fluorine, chlorine ester alachlor (cloransulam), diclofenac alachlor, double fluoride alachlor, metolachlor yl ethyl, metosulam fluoride sulfa grass , ethyl alachlor (pyrimisulfan), fluorine azole alachlor

[0098] 磺酰胺类除草剂：黄草灵、卡巴胺（cartasulam)、双氧威（fenasulam)、黄草消、五氟磺草胺、甲氧磺草胺、参见磺酰脲类除草剂 [0098] sulfonamide herbicide: asulam, Kabbah amine (cartasulam), fenoxycarb (fenasulam), oryzalin, five fluorine alachlor, pyroxsulam see sulfonylurea herbicides

[0099] 硫代酰胺类除草剂：酰苯草酮（bencartazone)、氯硫酰草胺 [0099] thioamide herbicides: benzophenone oxadiazon (bencartazone), chlorine thionyl alachlor

[0100] 抗生素类除草剂：双丙氨膦 [0100] antibiotics, herbicides: bialaphos

[0101] 芳族酸类除草剂： [0101] The aromatic acid herbicides:

[0102] 苯甲酸类除草剂：草灭平、麦草畏、2，3，6_TBA、三氯茴香酸 [0102] benzoic acid herbicides: grass off the flat, dicamba, 2,3,6_TBA, triclosan anisic acid

[0103] 嘧啶羟苯甲酸除草剂：双草醚、嘧草醚 [0103] pyrimidine-hydroxy benzoic acid herbicides: Two grass ether, ethyl ether grass

[0104] 嘧啶硫代苯甲酸除草剂：嘧草硫醚 [0104] pyrimidine sulfobenzate herbicides: ethyl sulfide grass

[0105] 邻苯二甲酸除草剂：敌草索 [0105] phthalic acid herbicides: diuron cable

[0106] 甲基吡啶酸除草剂：氯氨吡啶酸、二氯吡啶酸原、毒莠定 [0106] methyl pyridine acid herbicides: aminopyralid, clopyralid original, picloram

[0107] 喹啉羧酸除草剂：二氯喹啉酸、喹草酸 [0107] quinolinecarboxylic acid herbicides: quinclorac, quinmerac

[0108] 砷除草剂：二甲胂酸、0獻、05獻、六氟盐、獻六、獻獻、]\^獻、亚砷酸钾、亚砷酸钠 [0108] arsenic herbicides: cacodylate, 0 offer, 05 offer, six fluoride salt, offering six, Xian Xian,] \ ^ offer, potassium arsenite, sodium arsenite

[0109] 苯甲酰基环己二酮除草剂：甲基磺草酮、磺草酮、磺酰草吡唑、玉米除草剂 [0109] benzoyl cyclohexanedione herbicide: mesotrione, sulcotrione, sulfonyl pyrazole grass, corn herbicide

[0110] 苯并呋喃基烷基磺酸盐/酯除草剂：呋草黄、呋草黄 [0110] benzofuranyl alkyl sulfonate / ester herbicides: furosemide yellow grass, yellow grass furosemide

[0111] 苯并噻唑类除草剂：草除灵、噻草隆、噻唑禾草灵、苯噻草胺、噻唑隆 [0111] benzothiazole herbicides: Benazolin, thiophene diuron, thiazole diclofop, mefenacet, thiazole Long

[0112] 氨基甲酸盐/酯类除草剂：黄草灵、卡波灵（carboxazole)、氯脯灵(chlorprocarb)、苄胺灵、双氧威（fenasulam)、卡灵草、芽根灵 [0112] carbamate / ester herbicides: asulam, Kaposi Ling (carboxazole), chlorine preserved Ling (chlorprocarb), benzylamine spirit, fenoxycarb (fenasulam), Carling grass roots spirit bud

[0113] 笨基氨基甲酸盐/酯类除草剂：燕麦灵、BCPC、威磺灵（cartasulam)、雷克拉、 CEPC、氯草灵、氯苯胺灵、CPPC、双苯胺灵、棉胺宁、苯敌草、乙基苯敌草、苯胺灵、灭草灵 [0113] stupid base carbamate / ester herbicides: barban, BCPC, Wei Ling sulfonamide (cartasulam), Carbetamide, CEPC, chlorine grass Ling, Chlorpropham, CPPC, double aniline spirit, cotton amine Ning Diuron benzene, ethylbenzene diuron, aniline Ling, Ling herbicides

[0114] 环己烯肟类除草剂：禾草灭、丁苯草酮、烯草酮、克劳普草酮（cloproxydim)、噻草酮、环苯草酮、稀禾定、吡喃草酮、草酮 [0114] cyclohexene oxime herbicides: grasses off, SBR oxadiazon, clethodim, Kelao Pu oxadiazon (cloproxydim), thiophene grass ketone, benzene ring oxadiazon, sethoxydim, pyran oxadiazon , oxadiazon

[0115] 环丙基异Rlg唑除草剂：氯草酮、异恶唑草酮 [0115] cyclopropylisoxazole Rlg azole herbicides: chlorine oxadiazon, isoxaflutole

[0116] 二甲酰亚胺类除草剂：吲哚酮草酯、氟奋乃静（flumezin)、氟烯草酸、丙炔氟草胺、炔草胺（flumipropyn)、参见尿嘧啶除草剂 [0116] dicarboximide herbicide: cinidon ester, fluphenazine (flumezin), fluorine-ene oxalate, propynyl fluoro alachlor, flumipropyn (flumipropyn), see uracil herbicides

[0117] 二硝基苯胺除草剂：氟草胺、仲丁灵、挞乃、乙丁烯氟灵、氟消草、异乐灵、甲乐灵(methalpropalin)、磺乐灵、黄草消、二甲戊乐灵、氨氟乐灵、环丙氟灵、氟乐灵 [0117] dinitroaniline herbicides: fluorine alachlor, butralin, tart is, B butene fluorine spirit, fluoride elimination of grass, different spiritual music, spiritual music A (methalpropalin), sulfur spiritual music, oryzalin, pendimethalin, trifluralin ammonia, fluoride cyproterone spirit, trifluralin

[0118] 二硝基酚类除草剂：敌螨通、硝丙酚、二硝戊酚、地乐酚、乐消、DN0C、硝草酚、甲基特乐酯 [0118] dinitrophenols herbicides: enemy mites pass, nitrate propofol, two phenol amyl nitrate, dinoseb, music consumer, DN0C, pendimethalin phenol, methyl ester Kitt music

[0119] 二苯醚除草剂：氯氟草醚 [0119] diphenyl ether herbicides: Cellulose ether

[0120] 硝基苯醚除草剂：氟锁草醚、苯草醚、治草醚、甲氧除草醚、草枯醚、艾尼胺（etnipromid)、消草醚、乙羧氟草醚、氟除草醚、氟磺胺草醚、氟呋草醚、海罗胺(halosafen)、乳氟禾草灵、除草醚、三氟甲草醚、乙氧氟草醚 [0120] nitrobenzene ether herbicides: acifluorfen, aclonifen, Bifenox, methoxy nitrofen, CNP, Aini amine (etnipromid), eliminate grass ether, ethyl fluoroglycofen, fluorine nitrofen, fomesafen, furosemide fluoride grass ether, Jairo amine (halosafen), Lactofen, nitrofen, trifluoromethanesulfonic grass ether, oxyfluorfen

[0121] 二硫代氨基甲酸盐/酯类除草剂：棉隆、威百亩 [0121] dithiocarbamate salt / ester herbicides: dazomet, metam

[0122] 卤代脂族Qialogenated aliphatic)除草剂：阿罗酸（alorac)、茅滴混剂、茅草枯、氟丙酸、六氯丙酮、碘甲烷、溴甲烷、氯乙酸、SMA、TCA [0122] halogenated aliphatic Qialogenated aliphatic) herbicides: Arrow acid (alorac), Mao drops Mixture, dry grass, fluoride acid, hexachloroacetone, methyl iodide, methyl bromide, acid, SMA, TCA

[0123] 咪唑啉酮类除草剂：咪草酸、甲氧咪草烟、甲基咪草烟、咪唑烟酸、灭草喹、咪唑乙烟酸 [0123] imidazolinone herbicides: Mi oxalic acid, imazamox, imazapic, imazapyr, imazaquin, imazethapyr

[0124] 无机除草剂：氨基磺酸铵、硼砂、钙氯酸盐、硫酸铜、硫酸亚铁、钾重氮化合物、氰酸钾、叠氮化钠、氯酸钠、硫酸 [0124] Inorganic herbicides: ammonium sulfamate, borax, calcium chlorate, copper sulfate, ferrous sulfate, potassium diazo compound, potassium cyanate, sodium azide, sodium chlorate, sulfuric acid

[0125] 腈除草剂：溴波尼（bromobonil)、溴苯腈、羟敌草腈、敌草腈、碘波尼(iodobonil)、碘苯腈、双唑草腈 [0125] nitrile herbicides: bromine Pawnee (bromobonil), bromoxynil, hydroxy nitrile diuron, diuron nitrile, iodine Pawnee (iodobonil), ioxynil, double-yl oxabetrinil

[0126] 有机磷除草剂：甲基胺草磷、莎稗磷、地散磷、双丙氨膦、丁胺磷、2、4_DEP、DMPA、 EBEP、杀木磷、草铵膦（草铵膦-P)、草甘膦、哌草磷噪二唑酮类除草剂：恶唑隆、灭草定、稻思达、恶草酮 [0126] organophosphorus herbicides: methylamine phosphorus grass, anilofos, bensulide, bialaphos, butylamine phosphorus, 2,4_DEP, DMPA, EBEP, kill wood phosphorus, glufosinate (glufosinate -P), glyphosate, phosphorus noise oxadiazole piperazine grass herbicides: oxazole Long, methazole, rice Star, Oxadiazon

[0127] 噁唑类除草剂：异噁甲草威、异噁苯砜、异恶隆、异恶草胺、氯草酮、异恶唑草酮、单甲异噁隆、皮罗威（pyroxasulfone)、托普拉威（topramezone) [0127] oxazole herbicides: A grass Granville different evil, evil Phenylsulfonyl different, different evil Long, isoxaben, chlorine oxadiazon, isoxaflutole, single methyl isobutyl evil Long, Piluo Wei (pyroxasulfone ), Top Rahway (topramezone)

[0128] 含苯氧除草剂：杀草全、稗草胺、2，4-DEB、2，4_DEP、戊味禾草灵、滴硫钠、抑草蓬、 艾特尼普拉米（etnipromid)、芬特拉扣（fenteracol)、垂伏普斯（trifopsime) [0128] containing phenoxy herbicides: kill the whole grass, barnyard grass amine, 2,4-DEB, 2,4_DEP, E diclofop flavor, sodium sulfur droplets, weed suppression Peng, Ait Neep Lamy (etnipromid) , Fen Tela buckle (fenteracol), vertical V Phillips (trifopsime)

[0129] 苯氧基乙酸类除草剂：4气?六、2，4-0、3，4-0六、10^、10^-硫代乙酯、2，4，5-丁 [0129] phenoxy acid herbicides: 4 gas six, 2,4-0,3,4-0 six, 10 ^ 10 ^ - thio ester, 2,4,5-D?

[0130]苯氧基丁酸类除草剂：4-CPB、2，4-DB、3，4-DB、MCPB、2，4，5-TB [0130] phenoxy butyric acid herbicides: 4-CPB, 2,4-DB, 3,4-DB, MCPB, 2,4,5-TB

[0131] 苯氧基丙酸类除草剂：调果酸、4-CPP、2，4-滴丙酸（2，4_滴丙酸-P)、3，4_DP、2，4， 5-涕丙酸、甲氯丙酸、（甲氯丙酸-P) [0131] phenoxy acid herbicides: tune acid, 4-CPP, 2,4- Dichlorprop (2,4_ Dichlorprop -P), 3,4_DP, 2,4, 5- tears propionic acid, methyl chloropropionic acid, (A-chloropropionic acid -P)

[0132] 芳氧基苯氧基丙酸类除草剂：炔末灵(chlorazifop)、炔草酸、2-(4-(4-氯苯氧基）苯氧基）丙酸、氰氟草酯、禾草灵、恶唑禾草灵、（恶唑禾草灵-P)、噻唑禾草灵、 吡氟禾草灵、（吡氟禾草灵-P)、吡氟氯禾灵、（吡氟氯禾灵-P)、异恶草醚、恶唑酰草胺(metamifop)、喔草酯、喹禾灵、（喹禾灵-P)、垂伏普（trifop) [0132] aryloxy phenoxy acid herbicides: alkyne end Ling (chlorazifop), acetylene oxalic acid, 2- (4- (4-chlorophenoxy) phenoxy) propionic acid, cyhalofop, diclofop, fenoxaprop, (fenoxaprop -P), thiazole diclofop, fluazifop, (fluazifop -P), haloxyfop, (topiramate fluoride Chlorine Wo Ling -P), different evil grass ether, oxazole acid alachlor (metamifop), propaquizafop, quizalofop, (quizalofop -P), vertical V P (trifop)

[0133] 苯二胺类除草剂：敌乐胺、氨氟乐灵 [0133] benzene two herbicides: enemy Butralin, ammonia trifluralin

[0134] 吡唑类除草剂：四唑嘧磺隆、野燕枯、氟吡嘧磺隆、吡草胺、环醚吡嘧磺隆、吡嘧磺隆、皮罗威(pyroxasulfone) [0134] pyrazole herbicides: ethyl tetrazole, difenzoquat, flurbiprofen ethyl, metazachlor, cyclic ether-ethyl pyridine, ethyl pyridine, Piluo Wei (pyroxasulfone)

[0135] 苯酰吡唑类除草剂：批草酮、磺酰草吡唑、吡唑特、苄草唑、苯唑草酮 [0135] benzoylpyrazole herbicides: Batch oxadiazon, sulfuryl grass pyrazole, pyrazolinate, benzyl grass azole, oxacillin oxadiazon

[0136] 苯基吡唑类除草剂：异丙吡草酯、吡氯草胺、唑啉草酯、吡草醚 [0136] phenyl pyrazole herbicides: isopropyl ester grass topiramate, topiramate chlorine alachlor, pinoxaden, pyraflufen

[0137] 哒嗪类除草剂：哒草醚、哒草醇（pyridafol)、哒草特 [0137] pyridazine herbicides: da grass ether, da grass alcohol (pyridafol), pyridate

[0138] 哒嗪酮类除草剂：溴杀草敏、氯草敏、草哒酮、哒嗪氟草酯（flufenpyr)、二甲哒草伏、达草灭、草哒松、哒嗪酮乙酸 [0138] pyridazinone herbicides: herbicide sensitive bromine, chlorine sensitive grass, grass da ketone, pyridazine fluroxypyr ester (flufenpyr), dimethyl norflurazon, norflurazon, grass da song, pyridazinone acid

[0139] 吡啶类除草剂：氯氨基吡啶酸、一氯吡啶酯、二氯吡啶酸原、吡氟草胺、氟硫草定、 三吡氟草胺（flufenican)、氟草烟、氟啶草、毒莠定、氟吡酰草胺、氯草定、啶磺草胺、噻唑烟酸、绿草定 [0139] pyridine herbicides: aminopyralid acid, an ester-chloropyridine, clopyralid original, diflufenican, dithiopyr, three diflufenican (flufenican), fluroxypyr, haloxydine picloram, flurbiprofen acid alachlor, chlorine grass set, pyridine alachlor, thiazopyr, triclopyr

[0140] 嘧啶二胺类除草剂：氯胺草啶碱（iprymidam)、硫胺草啶碱（tioclorim) [0140] pyrimidine two herbicides: chloramine grass pyridine base (iprymidam), thiamine grass pyridine base (tioclorim)

[0141] 季铵除草剂：牧草快、1，1-二[2-( 二乙基氨基）-2-氧代乙基]-4，4-联吡啶(diethamquat)、野燕枯、敌草快、伐草快、百草枯 [0141] quaternary ammonium herbicides: pasture fast, 1,1-bis [2- (diethylamino) -2-oxo-ethyl] -4,4-bipyridine (diethamquat), difenzoquat, diuron fast, fast cutting grass, paraquat

[0142] 硫代氨基甲酸盐/酯类除草剂：苏达灭除草剂、草灭特、燕麦敌、EPTC、禾草畏、抑草威、异普林特（isopolinate)、甲禾草丹（methiobencarb)、草达灭、坪草丹、克草猛、苄草丹、稗草畏、草克死、禾草丹、仲草丹、野麦威、灭草猛 [0142] DITHIOCARBAMATES / ester herbicides: Minnesota off herbicides, especially off the grass, oats enemy, EPTC, fear grasses, weed suppression Viagra, iso Sprint (isopolinate), A Thiobencarb (methiobencarb), molinate, Dan Ping grass, grass grams fierce, prosulfocarb, pyributicarb, grass grams dead grasses Dan, Dan Chung grass, wild Maiwei, herbicides Meng

[0143] 硫代碳酸盐类除草剂：草灭散、E)(D、扑灭生 [0143] thiocarbonate herbicides: grass off loose, E) (D, born Fight

[0144] 硫脲类除草剂：灭草恒[0145] 三嗪类除草剂：杀草净、茚磺隆（indaziflam)、吡嘧磺隆、三羟基三嗪(trihydroxytriazine) [0144] thiourea herbicides: Herbicides constant [0145] triazine herbicides: kill grass net, indene metsulfuron (indaziflam), topiramate ethyl, trihydroxy-triazine (trihydroxytriazine)

[0146] 氯三嗪类除草剂：阿特拉津、可乐津、草净津、环草津、艾格林津（eglinazine)、草怕津、灭莠津（mesoprazine)、普赛津（procyazine)、甘扑津、扑灭津、另丁津、西玛津、特丁津、草达津 [0146] chlorine triazine herbicides: atrazine, cola Tianjin, cyanazine, ring Kusatsu, Eglin chun (eglinazine), grass afraid Tianjin, Tianjin destroy atrazine (mesoprazine), Phouesay chun (procyazine), Gan flutter Tianjin, Tianjin extinguished, another small, simazine, terbuthylazine, trietazine

[0147] 甲氧基三嗪类除草剂：阿特拉通、醚草通、扑灭通、密草通、西玛通、甲氧去草净 [0147] methoxy-triazine herbicides: atrazine through the ether through the grass, put out pass, through dense grass, Sima Tong, methoxy Terbutryn

[0148] 甲硫基三嗪类除草剂：莠灭净、叠氮净（aziprotryne)、氰草净、敌草净、异戊乙净、盖草津、扑草净、西草净、去草净 [0148] methylthio triazine herbicides: ametryn, azide net (aziprotryne), cyanide grass net, net diuron, iso-amyl acetate, net, cover Kusatsu, prometryne, simetryne, Terbutryn

[0149] 三嗪酮除草剂：胺嗪酮（ametridione)、胺嗪草酮（amibuzin)、环嗪酮、丁嗪草酮、 [0149] triazine herbicides: amine oxazinone (ametridione), amine metribuzin (amibuzin), hexazinone, Ding metribuzin,

苯嗪草酮、赛克津 Metamitron, metribuzin

[0150] 三唑类除草剂：杀草强、苯酮唑、三唑磺、氟胺草唑 [0150] triazole herbicides: amitrole, benzophenone, triazole sulfonamide, amine fluoride grass azole

[0151] 三唑酮类除草剂：氨唑草酮、酰苯草酮（bencartazone)、唑酮草酯、氟酮磺隆、卤苯胺唑（ipfencarbazone)、丙苯磺隆、甲磺草胺、酮磺吩酸（thiencarbazone) [0151] triazolone herbicides: ammonia carfentrazone ketone, benzophenone oxadiazon (bencartazone), trazodone grass esters, flucarbazone, halogen aniline azole (ipfencarbazone), propylene tribenuron, sulfentrazone, thiophene ketone sulfonic acid (thiencarbazone)

[0152] 三唑嘧啶类除草剂：氯酯磺草胺（cloransulam)、双氯磺草胺、双氟磺草胺、唑嘧磺草胺、磺草唑胺、五氟磺草胺、甲氧磺草胺 [0152] triazolopyrimidine herbicides: chlorine ester alachlor (cloransulam), diclofenac alachlor, double fluoride alachlor, metolachlor yl ethyl, metosulam pentafluorobenzoyl alachlor, methoxy alachlor

[0153] 尿嘧啶类除草剂：双苯嘧草酮、除草定、氟丙嘧草酯、丙嘧草酯（flupropacil)、异草定、环草定、嘧啶肟草醚、特草定 [0153] uracil herbicides: double benzene ethyl ketone grass, bromacil, -fluoropropoxy ethyl ester grass, grass ethyl propionate ester (flupropacil), Yi Cao set, ring set grass, saflufenacil, especially given the grass

[0154] 尿素类除草剂：噻草隆、苄草隆、环莠隆、氯双脲、氟吡草腙、异草完隆、异恶隆、噻唑隆、单甲异噁隆、草完隆 [0154] urea herbicides: thiophene diuron, benzyl diuron, atrazine ring Long, chlorine double urea, diflufenzopyr, Yi Cao End Long, Long different evil, thiazole Long, single methyl isobutyl evil Long, long grass finished

[0155] 苯基脲类除草剂：安尼隆（anisuron)、播土隆、氯溴隆、赤罗隆（chloreturon)、绿麦隆、枯草隆、杀草隆、枯莠隆、恶唑隆、敌草隆、非草隆、伏草隆、伏罗隆（fluothiuron)、异丙隆、利谷隆、灭草恒、甲基杀草隆、吡喃隆、秀谷隆、甲氧隆、绿谷隆、灭草隆、草不隆、对氟隆（parafluron)、稀草隆、环草隆、四氟隆、噻苯隆 [0155] phenyl urea herbicides: Anni Long (anisuron), sowing soil Long, Long chlorine bromine, red Luolong (chloreturon), chlortoluron, hay Long, Daimuron, dry herbicides Long, Long oxazole , diuron, fenuron, fluometuron, V Luolong (fluothiuron), isoproturon, linuron, herbicides constant, methyl Daimuron, pyran Long, Long Valley show, methoxy Long, Long Green Valley, monuron, not long grass on Freon (parafluron), sparse grass Long, siduron, PTFE Long, Thidiazuron

[0156] 磺脲类除草剂： [0156] sulfonylurea herbicides:

[0157] 嘧啶基磺酰脲类除草剂：酰嘧磺隆、四哔嘧磺隆、苄嘧磺隆、氯嘧磺隆、环丙嘧磺隆、乙氧嘧磺隆、啶嘧磺隆、氟吡磺隆、氟啶嘧磺隆、比甲酰胺磺隆、氟吡嘧磺隆、 唑吡嘧磺隆、甲基二磺隆、环醚吡嘧磺隆（metazosulfuron)、烟嘧磺隆、嘧苯胺磺隆(orthosulfamuron)、环氧嘧磺隆、氟嘧磺隆、丙嘧磺隆（propyrisulfuron)、吡嘧磺隆、砜嘧磺隆、甲嘧磺隆、将磺酰磺隆、三氟啶磺隆 [0157] pyrimidinyl sulfonylurea herbicides: acid ethyl, four beep-ethyl, bensulfuron, chlorimuron-ethyl, cyproterone ethyl, Ethoxysulfuron, pyridine-ethyl, flurbiprofen metsulfuron, fluorine-ethyl pyridine, Bijia amide metsulfuron, flurbiprofen ethyl, zolpidem ethyl, methyl two metsulfuron, cyclic ethers topiramate ethyl (metazosulfuron), nicosulfuron, ethyl aniline metsulfuron (orthosulfamuron), Oxasulfuron, primisulfuron, ethyl propionate (propyrisulfuron), topiramate ethyl, rimsulfuron, methyl ethyl, will sulfosulfuron, trifluoroacetic pyridine metsulfuron

[0158] 三嗪磺酰脲类除草剂：氯磺隆、醚磺隆、胺苯磺隆、碘磺隆（iodosulfuron)、甲磺隆、氟磺隆、噻吩磺隆、醚苯磺隆、苯磺隆、氟胺磺隆、三氟甲磺隆 [0158] triazine sulfonylurea herbicides: Chlorsulfuron, cinosulfuron, ethametsulfuron, iodine metsulfuron (iodosulfuron), metsulfuron, prosulfuron, thifensulfuron, triasulfuron, benzene metsulfuron, metsulfuron amine fluoride, trifluoromethanesulfonic Long

[0159] 噻二唑脲类除草剂：丁黄隆、磺噻隆、丁噻隆、噻氟隆、噻苯隆 [0159] thiadiazole urea herbicides: Dinghuang Long, Long thiophene sulfur, tebuthiuron, thiophene Freon, Thidiazuron

[0160] 未归类除草剂：丙烯醛、烯丙醇、环丙嘧啶酸、唑啶草酮、噻草平、苯并双环酮、 二环吡草酮（bicyclopyrone)、丁硫咪唑酮、氰氨化钙、卡姆本帝（cambendichlor)、伐草克、燕麦酯（chlorfenprop)、氟咪杀、整形醇、环庚草醚、异恶草酮、CPMF,甲酚、青氨、邻二氯苯、哌草丹、草藻灭、唑啶草、氟啶酮、氟咯草酮（flurochloridone)、呋草酮、嗪草酸甲酯、茚草酮、甲基异硫氰酸甲酯、0CH、去稗安、五氯酚、戊基恶唑酮、硝酸苯汞醋酸盐、甲硫磺乐灵、嘧啶肟草醚、环酯草醚、灭藻醌、硫氰苯胺、撒力卡品（sulglycapin)、噻二唑草胺(thidiazimin)、灭草环、三甲隆、垂普品丹（tripropindan)、草达克。 [0160] Uncategorized herbicides: acrolein, allyl alcohol, cyproterone pyrimidine acid, azole oxadiazon pyridine, thiophene grass flat, benzo bicyclic ketone, topiramate grass bicyclic ketone (bicyclopyrone), Ding imidazolidone sulfur, ammonia, cyanide calcium, Cam present Emperor (cambendichlor), cutting grass grams of oat ester (chlorfenprop), fluorine microphone kill, plastic alcohols, ethers cyclohepta grass, clomazone, CPMF, cresol, green ammonia, o-dichlorobenzene , dimepiperate, algae off the grass, grass azole pyridine, fluridone, fluorine slightly oxadiazon (flurochloridone), flurtamone, fluthiacet methyl indanofan, methyl isothiocyanate, methyl, 0CH, go Barnyard Ann, pentachlorophenol, amyl oxazolone, phenylmercuric nitrate acetate, methyl sulfur spiritual music, saflufenacil, pyriftalid, algae quinones, thiocyanate aniline, sprinkle force card product (sulglycapin) , thiadiazole alachlor (thidiazimin), herbicides ring, three long, vertical Cape goods Dan (tripropindan), grass Nasdaq. [0161] 上述除草剂和进一步鉴定和描述除草剂的链接，可参考http://WWW.alanW00d. net/pesticides/class_herbicides. html,其全文纳入本文。 [0161] The herbicide and links to further identify and describe the herbicide, refer to http: //WWW.alanW00d net / pesticides / class_herbicides html, incorporated herein in its entirety...

[0162] 在许多情况下，优选具有两性或阳性表面电荷的农药。 [0162] In many cases, the pesticide preferably has a positive or amphoteric surface charge. 该表面电荷特征可为所用农药所固有，或通过将合适的阳离子或两性离子表面活性剂应用于农药颗粒的表面而获得。 The surface charge characteristics can be obtained by a suitable cationic or zwitterionic surfactant applied to the surface of the pesticide particles obtained inherent pesticide used, or. 通常，基于总组合物中农药部分的总重（以100重量％计），表面活性剂的用量水平约为0. 01-10重量％ (优选约0. 1-3重量％ )。 Typically, based on the total weight of the total composition of pesticide portion (to 100% by weight), the level of surfactant is used in an amount of about 0. 01-10 wt% (preferably 1-3 wt%, about 0.1).

[0163] 合适的阳离子表面活性剂包括：二二十烷基二甲基氯化铵；二二十二烷基二甲基氯化铵；二（十八烷基（dioctadecyidimethyl)) 二甲基氯化铵；二（十八烷基）二甲基甲磺酸铵；二（十四烷基）二甲基氯化铵和上述脂肪基团的天然产生的混合物，例如，二（氢化动物脂）二甲基氯化铵；二（氢化动物脂）二甲基甲磺酸铵（metho-sulphate) ；二动物脂二甲基氯化铵；二油烯基二甲基（dioleyidimethyl)氯化铵。 [0163] Suitable cationic surfactants include: two twenty-alkyl dimethyl ammonium chloride; twenty-two dodecyl dimethyl ammonium chloride; two (octadecyl (dioctadecyidimethyl)) two methyl chloride ammonium; di (stearyl) dimethyl ammonium methanesulfonate; mixture of di (tetradecyl) dimethyl ammonium chloride, and said aliphatic group of naturally occurring, e.g., di (hydrogenated tallow) dimethyl ammonium chloride; di (hydrogenated tallow) dimethyl ammonium sulfonate (metho-sulphate); two tallow dimethyl ammonium chloride; Dioleyl dimethyl (dioleyidimethyl) chloride.

[0164] 这些阳性表面活性剂也包括咪唑啉锡化合物，例如1-甲基-1-(动物脂基酰胺基-)乙基-2-动物脂基4，5-二氢甲磺酸咪唑啉.锡和1-甲基-1-(棕榈酰基酰胺基）乙基-2-十八烷基4，5-二氢甲磺酸咪唑啉银。 [0164] These positive surfactants also include imidazoline tin compounds, such as 1-methyl-1- (tallow amido -) ethyl-2-tallow imidazoline-4,5-dihydro-methanesulfonic acid tin and 1-methyl-1- (palmitoyl-amido) ethyl-2-stearyl imidazoline methanesulfonic acid 4,5-dihydro-silver. 其他有用的咪唑啉鐺材料为2-十七烷基-1-甲基-1 (2-硬脂酰胺基）-乙基-甲磺酸咪唑啉锡和2-十二烷基-1-羟乙基-1-油烯基-氯化咪唑啉锚。 Other useful imidazolinium materials are 2-heptadecyl-pan-1-methyl-1 (2- stearamide yl) - ethyl - imidazoline tin methanesulfonate and 2-dodecyl-l-hydroxybutane ethyl-1-oleyl - imidazoline chloride anchor.

[0165] 其他合适阳性表面活性剂的示例包括：二烷基（C12-C2》二甲基氯化铵；烷基(椰油)二甲基苄基氯化铵；十八胺乙酸盐；十四胺乙酸盐；动物脂烷基丙二胺乙酸盐； 十八烷基三甲基氯化铵；烷基（动物脂）三甲基氯化铵；十二烷基三甲基氯化铵；烷基（椰油）三甲基氯化铵；十六烷基三甲基氯化铵；联苯基三甲基氯化铵，烷基（动物脂）咪唑啉季盐；十四烷基甲基苄基氯化铵；十八烷基二甲基苄基氯化铵；二油烯基二甲基氯化铵•'聚氧乙烯十二烷基一甲基氯化铵；聚氧乙烯烷基（C12-C2》苄基氯化铵；聚氧乙烯十二烷基一甲基氯化铵；1-羟乙基-2-烷基（动物脂）_咪唑啉季盐；和具有硅氧烷基团作为疏水基团的硅酮阳性表面活性剂，具有氟烷基基团作为疏水基团的含氟阳离子表面活性剂。 [0165] Other suitable surfactants of the positive examples include: dialkyl (C12-C2 "dimethyl ammonium chloride; alkyl (coconut) dimethyl benzyl ammonium chloride; octadecylamine acetate; fourteen amine acetate; tallow alkyl propylene diamine acetate; octadecyl trimethyl ammonium chloride; alkyl (tallow) trimethyl ammonium chloride; Dodecyl trimethyl chloro ammonium; alkyl (coconut) trimethylammonium chloride; cetyl trimethyl ammonium chloride; biphenylyl trimethyl ammonium chloride, alkyl (tallow) imidazoline quaternary salt; fourteen alkyl dimethyl benzyl ammonium chloride; octadecyl dimethyl benzyl ammonium chloride; dioleyl dimethylammonium chloride • 'polyoxyethylene lauryl monomethyl ammonium chloride; poly polyoxyethylene alkyl (C12-C2 "benzyl ammonium chloride; polyoxyethylene lauryl monomethyl ammonium chloride; 1- hydroxyethyl-2-alkyl (tallow) imidazoline quaternary salt _; and having a siloxane group as the hydrophobic group of positive silicone surfactant having a fluoroalkyl group as the hydrophobic group of the fluorine-containing cationic surfactant.

[0166] 两性（两性离子）表面活性剂在酸性或碱性介质中在分子的亲水部分具有阳性、阴性、或两种电荷。 [0166] amphoteric (zwitterionic) surfactant in an acidic or alkaline medium having a positive, negative, or both charges in the hydrophilic portion of the molecule. 可以使用任意合适的两性表面活性剂。 You can use any suitable amphoteric surfactants. 例如可使用氨丙酸盐(aminoproprionate)，其中所述氨丙酸盐的烷基链优选约C. 4和约C. 12且可为支链或直链。 For example using ammonia propionate (aminoproprionate), wherein the amino acid salt is preferably an alkyl chain of from about about C. 12 C. 4 and may be branched or straight chain. 所述氨丙酸盐也可以是烷基氨丙酸钠。 The ammonia may be propionates alkylamino propionate. 市售代表产品以商品名MIRATAINE JC-HA销售。 Representative products marketed under the trade name MIRATAINE JC-HA sales.

[0167] 其他合适的两性表面活性剂包括，二丙酸盐例如Mirataine H2C-HA、磺基甜菜碱(sultaines)例如Mirataine ASC、甜菜喊例如Mirataine BET-0—30、氧化胺例如Barlox 12i和醋酸盐形式的两性咪唑啉衍生物Miranol JEM Cone、二丙酸盐形式的Miranol C2M-SF Conc.)、和磺酸盐如Miranol JS Conc.。 [0167] Other suitable amphoteric surfactants include, dipropionate e.g. Mirataine H2C-HA, sulfobetaines (sultaines) e.g. Mirataine ASC, beet call e.g. Mirataine BET-0-30, and amine oxides such as Barlox 12i vinegar salt form of amphoteric imidazoline derivatives Miranol JEM Cone, dipropionate form Miranol C2M-SF Conc.), and salts such as Miranol JS Conc ..

[0168] 两性表面活性剂的其他示例包括氨基酸、甜菜碱、磺基甜菜碱、磺酸甜菜碱(sulfobetaines)、脂肪酸的羧酸盐和磺酸盐、磷酸甜菜碱、咪唑鐺衍生物、大豆磷脂、蛋黄卵磷脂，下列碱金属盐、碱土金属盐、铵盐或取代的铵盐：烷基两性羧基甘氨酸盐和烷基两性羧基丙酸盐、烷基两性二丙酸盐、烷基两性二乙酸盐、烷基两性甘氨酸盐和烷基两性丙酸盐，其中烷基代表具有6-20碳原子的烷基基团；具有12-18个碳原子的烷基亚氨基丙酸盐、 烷基亚氨基二丙酸盐和烷基两性丙基磺酸盐；烷基甜菜碱和酰氨基丙基甜菜碱和烷基磺基甜菜碱和烷基酰氨基丙基羟基磺酸甜菜碱，其中烷基代表具有6-20碳原子的烷基基团。 [0168] Other examples of amphoteric surfactants include amino acid, betaine, sulfo betaine, betaine sulfonate (sulfobetaines), fatty acid carboxylates and sulfonates, phosphoric acid betaine, pan imidazole derivatives, soy lecithin , egg yolk lecithin, the following alkali metal salts, alkaline earth metal, ammonium or substituted ammonium salts of: alkyl amphoteric carboxy glycinate amphoteric carboxyl and alkyl propionates, alkyl amphoteric dipropionate, alkyl amphoteric diethyl acid salts, alkyl and alkyl amphoteric glycinate amphoteric propionates, wherein the alkyl group represents an alkyl group having 6-20 carbon atoms; alkylimino propionate having 12 to 18 carbon atoms, an alkyl group iminodipropionates and alkyl amphoteric propyl sulfonates; alkyl betaines and amidopropyl betaines and alkyl sultaines and alkylamido propyl betaine hydroxy acid, wherein the alkyl group Representative having 6-20 carbon atoms, alkyl group. [0169] 如上所述，本发明的共聚物包括相应量的衣康酸和马来酸部分。 [0169] As described above, the present invention comprises a copolymer of a corresponding amount of itaconic acid and maleic acid moiety. 这些共聚物可以酸形式存在，作为部分盐或饱和盐。 These copolymers can be in the acid form, or as a partial salt saturated saline. 使用盐时，几乎可用任何所需的阳离子物质形成该盐， 具体的是碱金属和碱土金属如钠、钾或钙盐。 When salt is used, virtually any available material having the desired cationic salt, particularly the alkali metals and alkaline earth metals such as sodium, potassium or calcium salts.

[0170] 本发明的共聚物如美国专利号第6，515，090和6，706，837号所述，二者通过引用完全和完整地纳入本文，特别应用了所述'837专利的操作实施例。 [0170] The copolymer of the present invention as described in U.S. Patent No. 6,515,090 and No. 6,706,837 the first, both by reference in its entirety and fully incorporated herein, in particular the application of the '837 patent operation as in cases. 通常，所述共聚物应所需地包含约10-90重量％的马来酸部分（优选约25-75%重量），和相应的约90-10重量％ 的衣康酸部分（优选约75-25重量％)。 Typically, the copolymer should desirably contain from about 10-90% by weight of a maleic acid moiety (preferably about 25-75% by weight), and corresponding to about 90-10% by weight of itaconic acid portion (preferably about 75 -25 wt%). 此类中特别优选的一种共聚物为美国密苏里州的贝尔顿市（Belton，M0)专业肥料产品有限公司（Specialty Fertilizer Products,LLC)以商标AVAIL®所售的共聚物，其为衣康酸和马来酸酐的部分基本等摩尔量的40重量％固体水性共聚物分散剂，用钠离子进行部分中和（CAS#556055-76-6)，pH值为6_8。 Such a particularly preferred copolymers Belton City, Missouri (Belton, M0) specialty fertilizer products Limited (Specialty Fertilizer Products, LLC) sold under the trademark AVAIL® copolymer, which is itaconic acid maleic anhydride, and some substantially equimolar amount of 40% by weight solids aqueous copolymer dispersant, the sodium ions with partially neutralized (CAS # 556055-76-6), pH value 6_8.

[0171] 本发明的农药组合物中的共聚物含量可在很宽的范围内不同，且主要考虑之一是共聚物的成本。 [0171] In the copolymer content of the pesticide composition of the present invention may vary within a wide range of different and are one of the main consideration is the cost of the copolymer. 通常，基于所述农药组合物总重量（以100重量％计），所述共聚物应以0.05-10重量％的水平存在（优选0. 1-4重量％，且最优选0. 2-2重量％ )。 Typically, (based on 100% by weight), the copolymer should be present at a level from 0.05 to 10% by weight (preferably 0. 1-4 weight based on the total weight of the pesticide composition%, and most preferably 0. 2-2 % by weight).

[0172] 所述共聚物优选以部分盐或饱和盐的形式使用。 [0172] The copolymer is preferably used in the form of a salt or a partially saturated salt. 这通过添加碱性材料如氢氧化钠或氢氧化钙以产生约5-9、优选约6-8的pH而形成。 This is achieved by addition of an alkaline material such as sodium hydroxide or calcium hydroxide to produce about 5-9, preferably pH about 6-8 is formed. 也可用较低pH酸性或部分盐的共聚物，特别是对于选定单体比率和农药而言。 May also be an acidic or lower pH partial salts of copolymers, especially for the selected monomer ratio and in terms of pesticides. 通常，所述PH应为约2-8。 Typically, the PH should be about 2-8.

[0173] 仅含非常少量的共聚物佐剂的本发明农药组合物可以以与所述无佐剂的标准农药产品相同的水平使用。 [0173] copolymers containing only very small amounts of the pesticide adjuvant compositions of the invention may be with the non-adjuvanted standards use the same level of pesticide products. 这些水平在不同农药之间不同，且使用水平本领域已知。 These different levels between different pesticides, and known in the art using the horizontal. 但是，由于所述共聚物的协同效应，所以适宜较少的使用水平。 However, due to the synergistic effect of the copolymer, it is appropriate to use fewer levels.

[0174] 与单独使用等量的所选农药相比，本发明的组合物和方法提供更高的农药效果。 [0174] Compared with the same amount of the selected individual pesticides, compositions and methods of the present invention provide higher pesticide effect. 这种提高优选是至少约3倍高的效果，更优选是四倍高的效果。 This increase is preferably at least about 3-fold higher effect, more preferably four times as high effect.

[0175] 下述实施例阐述了本发明优选的组合物和其农药用途。 EXAMPLES [0175] The following describes the preferred compositions of the present invention and their pesticidal use. 然而应理解，这些实施例是阐述性的，其所含的任何内容都不应视作对本发明整体范围的限制。 However, it should be understood that these embodiments are illustrative, and any content contained therein should be construed as limiting the overall scope of the invention.

[0176] 实施例1 [0176] Example 1

[0177] 在本实施例中测试了不同稀释水平和含有或不含有优选共聚物的一系列市售的杀虫剂，所述共聚物为前述AVAIL ®共聚物（马来酸酐/衣康酸共聚物饱和钠盐在水中的40 % -60 % w/w水性组合物)。 [0177] tested different dilution levels and insecticide or may not contain a series of commercially available copolymers of the present preferred embodiment, the copolymer is a copolymer of the preceding AVAIL ® (maleic anhydride / itaconic acid copolymer saturated sodium salt in water was 40% -60% w / w aqueous composition). 每组测试运行中，用火焰蚁群体测试所选的杀虫剂，测量杀死整个群体所需的时间。 Each test run, the test flame ant colony selected pesticides, measuring the entire group needed to kill time. 如上所述，所述共聚物的存在产生不同的佐剂效果且显著的提高了所述杀虫剂的威力。 As described above, the presence of the copolymer produced in different adjuvant effect and significantly improves the power of the pesticide.

[0178] 具体地，各测试运行中在玻璃瓶罐中加入20ml相应液体杀虫剂组合物并围着其内底部旋转。 [0178] Specifically, each test run adding 20ml liquid insecticide composition corresponding Bolipingguan and rotate around its inner bottom. 然后倒出所述液体，使剩余物在罐内表面上干燥，产生基本单体的干燥层。 The liquid is then decanted, and the residue was dried on the tank surface, to produce substantially dry layer monomers. 用滑石涂覆所述罐外颈表面，且所述罐的开口端放入火焰蚁巢。 Talc coated outer surface of the neck of the tank, and the open end of the canister into the flame nest. 所述滑石涂层阻止好斗的火焰蚁爬到所述罐的外表面。 The talc coating prevents flame aggressive ants climb the outer surface of the tank. 因此火焰蚁种群建立在各罐中，然后用有孔玻璃罐盖给所述罐加盖。 Fire ant populations thus established in the tank, and a glass lid with a hole to affix the tank. 记录所有火焰蚁致命时间。 Fatal fire ants all time record.

[0179] 在各情况中，制备杀虫剂的推荐浓度（记录为“IX”），随后用水稀释以产生稀释的组合物。 [0179] In each case, the recommended concentration in the preparation of pesticides (recorded as "IX"), then diluted with water to produce a diluted composition. 使用共聚物时，以30ml/加仑的水平加入所述共聚物并温和搅拌。 When a copolymer is used, in order to 30ml / gallon level of the copolymer is added with gentle stirring. 若需要，可使用较低量的共聚物，如20ml/加仑。 If desired, the use of lower amounts of copolymer, such as 20ml / gallon.

[0180] 下述表格显示这些测试的结果。 [0180] The following table shows the results of these tests.

[0181]魁[0182] [0181] Quebec [0182]

[0183] 表1的数据清晰的给出了所述共聚物对所测杀虫剂的佐剂效果。 Data [0183] Table 1 clearly shows the adjuvant effect of said copolymer measured insecticides. 在所有情况中， 杀虫剂的最低有效水平的致命时间由于存在所述共聚物而大大降低。 In all cases, the minimum effective level of pesticide lethal time due to the presence of the copolymer greatly reduced. 尽管不完全了解这种效果的机制，但是可以认为具有两性或阳性电荷的所测杀虫剂被所述共聚物修饰而改变其膜电位，如所述共聚物聚集所述电荷，从而使所述杀虫剂/共聚物混合物更有效。 Although the mechanism of this effect is not fully understood, but is considered the measured insecticide amphoteric or positive charges of the copolymer having been modified to alter their membrane potential, such as the copolymer of the charge accumulation, so that the Insecticides / copolymer mixture is more effective. 这通过使用具有阴性电荷的杀虫剂（Diazinon®)的一系列测试得以证实，其中与所述杀虫剂自身相比，所述共聚物没有降低致命时间。 Pesticides (Diazinon®) which has a negative charge by using a series of tests were confirmed, which compared with the insecticide itself, the copolymer does not reduce the lethal time.

[0184] 实施例2 [0184] Example 2

[0185] 在另一系列测试中，用具有不同比例的马来酸酐和衣康酸组分的各种共聚物与杀虫剂在不同PH水平进行测试。 [0185] In another series of tests, with maleic anhydride and itaconic acid component and various copolymers having different ratios of insecticides in different PH levels tested. 具体地，相应共聚物组合物由聚马来酸、1 ： 3重量比的马来酸酐和衣康酸、1 ： 1重量比的马来酸酐和衣康酸、3 ： 1重量比的马来酸酐和衣康酸、7 ： 1 重量比的马来酸酐和衣康酸所制备。 Specifically, the copolymer composition by corresponding polymaleic acid, 1: 3 weight ratio of maleic anhydride and itaconic acid, 1: 1 weight ratio of maleic anhydride and itaconic acid, 3: 1 weight ratio of maleic anhydride and itaconic acid, 7: 1 weight ratio of maleic anhydride and itaconic acid are prepared. 然后用氢氧化钠对这些共聚物各自的单独部分进行PH 调节，以为各共聚物提供具有PH未调节的部分以及pH调节为6、7和8的部分。 Then neutralized with sodium hydroxide to a respective separate portion of these copolymer PH regulator, provided that each copolymer having a PH portion and unmodulated portion is adjusted to pH 6, 7 and 8. 然后以每加仑杀虫剂30ml共聚物的水平将这些经pH调节的测试共聚物与1/100X稀释的马拉息昂混合。 Then 30ml copolymer per gallon pesticide levels these tests copolymers pH adjusted with malathion mix 1 / 100X dilution. 相似地，然后也以每加仑杀虫剂30ml共聚物的水平将相同的经pH调节的共聚物与1/20X水稀释的除虫菊酯混合。 Similarly, and also insecticides 30ml per gallon horizontal copolymer pH adjusted to the same copolymer was mixed with 1 / 20X dilution water pyrethrins.

[0186] 然后将所述测试产物用于实施例1中相同的火焰蚁杀死实验，产生表2和表3的数据。 [0186] The test product was then used in Example 1 in the same fire ant embodiment kill experiments, generating data in Table 2 and Table 3.

[0187] 表2[0188] [0187] Table 2 [0188]

[0190]表 3 [0190] Table 3

[0191] [0191]

[0192] [0192]

[0193] 表2和3的数据证明优选的共聚物在较宽范围的不同马来酸酐/衣康酸比例都有用，且所述共聚物在较宽的PH范围中同样有效。 Data [0193] Table 2 and 3 prove preferred copolymer in a wide range of different maleic anhydride / itaconic acid ratio are used, and the copolymer in a wide range of PH equally effective.

[0194] 实施例3 [0194] Example 3

[0195] 在此实施例中，用草甘膦除草剂测试本发明共聚物的有效性。 [0195] In this embodiment, the present invention is used to test the effectiveness of the herbicide glyphosate copolymer. 用爱荷华州地区具有高约18英尺的混合雀麦草和野茅的准备种植玉米的田地作为测试地。 Iowa region with a high of about 18 feet of mixed wild Mao Brome and prepare fields for planting corn as a test ground. 为了种植，其需要杀死杂草。 In order to grow, it needs to kill the weeds. 已知仅用一种草甘膦应用很难有效杀灭。 Known only difficult to effectively kill glyphosate application.

[0196] 本测试中，2夸脱标准市售草甘膦与40加仑观％氮液体肥料混合，所述肥料由1/3 重量的尿素、1/3重量的硝酸铵和1/3重量的水组成。 [0196] For this test, two quarts standard commercial glyphosate View% nitrogen and 40 gallons of liquid fertilizer mix, the weight of urea fertilizer by 1/3, 1/3 by weight of ammonium nitrate and 1/3 by weight water. 作为对比，2夸脱40%重量的固体马来酸酐/衣康酸共聚物（专业肥料产品有限公司销售的用于液体的Nutrisphere ®，马来酸-衣康酸共聚物钙盐，30% -60% w/w水溶液，pH 1. 5)加入单独量的所述草甘膦补充肥料中。 In contrast, two quarts of 40% solids by weight of maleic anhydride / itaconic acid copolymer (specialty fertilizer products Co., for liquid Nutrisphere ®, maleic acid - itaconic acid copolymer calcium, 30 percent - 60% w / w aqueous solution, pH 1. 5) was added an amount of said glyphosate alone supplemental fertilizer.

[0197] 以10加仑/英亩的比例将两种测试组合物喷洒在所述田地的临近测试区。 [0197] to 10 gallons / acre composition ratio of the two tests in the field of spray near the test area. 10天后，喷洒所述草甘膦和共聚物-补充的肥料的区域的草基本上完全杀灭。 10 days later, said spraying glyphosate and copolymer - supplementary fertilizer grass area substantially complete kill. 对于不含共聚物的草甘膦-补充的肥料，需要第二次草甘膦喷洒应用才能完全杀灭。 For free copolymer glyphosate - add fertilizer, need a second application of glyphosate spray to completely kill.

[0198] 因此，本发明的共聚物使种植提前且降低草甘膦消耗。 [0198] Accordingly, the present invention enables cultivation of the copolymer in advance and reduce the consumption of glyphosate.