发明内容 SUMMARY

[0008] 本发明克服了上述问题并提供含相应量的农药和共聚物的农药组合物，所述共聚物含各自含量的马来酸和衣康酸组分。 [0008] The present invention overcomes the above problems and to provide a pesticidal composition containing a pesticide and a corresponding amount of the copolymer, the copolymer of maleic acid and itaconic acid component containing their content. 所述农药组分可为任何具有农药活性的试剂（如除草剂、杀虫剂、杀真菌剂和杀线虫剂）且优选选自杀虫剂、除草剂、及其混合物的组。 The pesticide component can be any agent having pesticidal activity (such as herbicides, insecticides, fungicides and nematicides) and is preferably selected from insecticides, herbicides, and mixtures of. 公知的拟除虫菊酯和有机磷酸酯农药以及草甘膦除草剂适于用在本发明中。 Known pyrethroid and organophosphate pesticides and glyphosate herbicide suitable for use in the present invention.

[0009] 本发明优选的共聚物佐剂为含马来酸和衣康酸组分的共聚物，所述组分通常源自相应的酸或酸酐。 [0009] Preferred copolymers of the present invention, the adjuvant containing maleic acid and itaconic acid copolymer component, the component is typically derived from the corresponding acid or anhydride. 虽然其他单体也可用在所述马来酸-衣康酸共聚物中，但优选这些单体仅以极少含量存在，最多约7重量％，优选最多约4重量％。 While other monomers may also be used in the maleic acid - itaconic acid copolymer, but preferably the content of these monomers exist only rarely, up to about 7% by weight, preferably up to about 4% by weight. 反过来说，所述共聚物应含至少约93重量％、优选至少约96重量％的衣康酸和马来酸单体。 Conversely, the copolymer should contain at least about 93% by weight, preferably at least about 96% by weight of itaconic acid and maleic acid monomers. 最优选地，所述共聚物主要或全部由马来酸和衣康酸组分组成。 Most preferably, the copolymer composed primarily or exclusively from maleic acid and itaconic acid component. 此外，虽然其他聚合物或共聚物可形成本发明组合物的部分，在优选方面，所述衣康酸/马来酸共聚物在所述组合物中是优势聚合物组分。 Moreover, although other polymer or copolymer of the composition of the present invention can be formed, in a preferred aspect, the itaconic acid / maleic acid copolymer is an advantage of the polymer component in the composition. 通常，所述组合物包括相应的农药部分和聚合物部分，以聚合物部分总重为100重量％计，所述聚合部分具有至少约60重量％ (更优选至少约80重量％，且最优选至少约90重量％ ) 的所述优选衣康酸/马来酸共聚物。 Typically, the composition comprising a polymer and a corresponding portion of some pesticides, part of the total weight of the polymer to 100 wt% of the polymeric portion having at least about 60 wt% (more preferably at least about 80% by weight, and most preferably at least about 90% by weight) of the preferred itaconic acid / maleic acid copolymer. 最优选地，所述聚合物部分主要由所述衣康酸/马来酸共聚物组成，即其基本不含其他类型单体。 Most preferably, the polymer is mainly composed of the itaconic acid / maleic acid copolymer, which is substantially free of other types of monomers.

[0010] 本发明的组合物基本可用于必须或需要农药性能的任何环境，如土壤或叶片应用的农业使用，或用在硬表面如室内或建筑物虫害控制同样，可用任何已知的方法将所述组合物作为液体或固体使用。 Hard surfaces such as indoor pest control or building the same, by any known method [0010] The compositions of the invention can be used in substantially any environment or must require pesticide properties, such as soil or blade application of agricultural use, or for use in the the composition is used as a liquid or a solid. 在农业应用中，所述组合物优选是适于播撒喷雾应用的水分散体或溶液。 In agricultural applications, the composition is preferably adapted to spread the spray application of an aqueous dispersion or solution. 通常，与等量的无本文共聚物佐剂或添加剂的农药相比，本发明组合物提供至少约2倍、更优选至少约3倍的更强的农药有效性。 Typically, the pesticide as compared to no additives or adjuvants copolymers herein an equal amount of a composition of the present invention provide at least about 2-fold, more preferably greater effectiveness of the pesticide at least about 3-fold.

[0011] 优选实施方式的详述 [0011] Detailed Description of the preferred embodiments

[0012] 本发明依据的发现是共聚物佐剂或添加剂可显著改善广谱农药的有效性。 [0012] The present invention is based on discovery is a copolymer adjuvants or additives can significantly improve the effectiveness of broad-spectrum pesticides. 最需要地，所述共聚物与所述农药混合以形成混合物，然后可将该混合物应用于土壤、在叶片应用中、在硬表面上、作为气雾剂、作为液体或固体组合物的添加剂（如肥料）、或在需要农药活性的任何其他环境中。 Most needed, said pesticide with the copolymer to form a mixture, the mixture may then be applied to the soil, in leaf application, on a hard surface, as an aerosol, as a liquid or solid composition additives ( such as fertilizer), or in any other environment in need pesticidal activity. 或者，所述农药和共聚物可同时或顺序（通常在彼此的24小时内） 应用于土壤。 Alternatively, the pesticide and copolymer may be simultaneously or sequentially (usually within 24 hours of each other) is applied to the soil. 在使用混合组合物的情形，该组合物通常为水分散剂或溶液的形式，一般含水、农药、和共聚物组分。 In the case of using the mixed composition, the composition is typically in the form of aqueous dispersions or solutions, generally aqueous, pesticides, and a copolymer component. 其他少量成分也可用在组合物中，如表面活性剂和PH调节剂，或任何其他前述本领域已知的佐剂或添加剂。 Additional minor components can also be used in the composition, such as surfactants and a PH adjusting agent, or any other known in the art of the foregoing additives or adjuvants.

[0013] 本发明的组合物中所用的农药广泛选自杀虫剂和除草剂。 [0013] The pesticidal composition of the present invention is used in a wide range of selected pesticides and herbicides. 对于杀虫剂，尤其优选合成除虫菊酯和有机磷酸酯。 For pesticides, particularly preferably pyrethroids and organophosphates. 例如，氯菊酯（C21H20C1203,（3-苯氧基苯基）甲基3-(2, 2- 二氣乙烯基）-2,2- 二甲基_环丙烷_1_駿酸醋，CAS#52645-53-l)和联苯姻醋(C23H22C1F302,（2-甲基-3-苯基苯基）甲基（lS，3S)-3-[(Z)-2-氯-3,3,3-三氟丙-1-烯基]-2,2-二甲基环丙烷-1-羧酸酯，0六5#82657-04-3)为合适的除虫菊酯类。 For example, permethrin (C21H20C1203, (3- phenoxyphenyl) methyl 3- (2, 2-gas) -2,2-dimethyl-cyclopropane _1_ _ Chun vinegar, the CAS # 52645-53-l) biphenyl, and benzoin acetate (C23H22C1F302, (2- methyl-3-phenyl) methyl (lS, 3S) -3 - [(Z) -2- chloro-3,3,3 , 3-trifluoromethyl-1-enyl] -2,2-dimethyl-cyclopropane-1-carboxylate, six 5 0 # 82657-04-3) is a suitable pyrethrins. 本发明所用的典型有机磷酸酯农药为马拉硫磷（C10H1906PS2,2-(二甲氧硫膦基硫代）丁二酸二乙酯， CAS#121-75-5)〇 Typical organophosphate pesticides used in the present invention as malathion (C10H1906PS2,2- (dimethoxyphenyl sulfur phosphine-ylthio) succinic acid diethyl ester, CAS # 121-75-5) billion

[0014] 更普遍地，本发明使用下述杀虫剂： [0014] More generally, the present invention is the use of the following pesticides:

[0015] 抗生素杀虫剂：阿洛氨菌素、苏云金素 [0015] Antibiotics Pesticides: Alor ammonia streptozotocin, thuringiensin

[0016] 大环内酯杀虫剂 [0016] macrocyclic lactone insecticides

[0017]阿弗耒菌素杀虫剂:阿巴美丁、多柃克丁、埃玛菌素、依立诺克丁、彳尹维菌素、司拉克丁 [0017] Alfred Lei avermectin insecticides: abamectin, more Eurya abamectin, emamectin, eprinomectin, ivermectin left foot Yin, Lake Ding Division

[0018] 米尔倍霉素杀虫剂:勒皮克丁(Iepimectin)、尔倍克丁（ilbemectin)、米尔倍霉素肟化物、莫昔克丁 [0018] milbemycin insecticides: Le Puy g of (Iepimectin), Seoul times g of (ilbemectin), milbemycin oxime compound, moxidectin

[0019] 多杀菌素类杀虫剂:斯平托姆(spinetoram)、多杀菌素（spinosad) [0019] spinosad insecticide: Spinney Thom (spinetoram), spinosad (spinosad)

[0020] 含砷杀虫剂：砷酸钙、乙酰亚砷酸铜、砷酸铜、砷酸铅、砷酸钾、砷酸钠 [0020] Pesticides containing arsenic: arsenic, calcium acetyl copper arsenite, copper arsenate, lead arsenate, arsenic, potassium, sodium arsenate

[0021] 植物性杀虫剂：安纳巴松、印苦楝子素、右旋烯、烟碱、除虫菊素（瓜菊酯（瓜菊酯I、瓜菊酯II)、茉莉菊酯I、茉莉菊酯II、除虫菊素I、除虫菊素II)、苦味液、鱼藤酮、鱼尼丁、 沙巴达子 [0021] botanical insecticide: Anna Bason, azadirachtin prime, D-ene, nicotine, pyrethrin (melon pyrethroid (permethrin melon I, Cinerin II), jasmine permethrin I, chrysanthemum jasmine ester II, pyrethrin I, pyrethrin II), Angostura, rotenone, fish Nitin, Saporta child

[0022] 氨基甲酸盐/酯杀虫剂：恶虫威、西维因 [0022] carbamate / ester insecticide: bendiocarb, carbaryl

[0023] 苯并呋喃基甲基氨基甲酸盐/酯杀虫剂：丙硫克百威、虫螨威、呋喃威、单甲基克百威（decarbofuran)、咲线威 [0023] benzofuranyl methyl carbamate / ester insecticide: benfuracarb, carbofuran, furan Granville, monomethyl carbofuran (decarbofuran), Kou Wei line

[0024] 二甲基氨基甲酸盐/酯杀虫剂：地麦威、敌绳威、海驱威（hyquincarb)、抗虫牙威 [0024] dimethyl carbamate / ester insecticide: to Maiwei enemy Shengwei, sea flooding Granville (hyquincarb), insect-resistant teeth Granville

[0025] 氨基甲酸肟盐/酯杀虫剂：棉铃威、涕灭威、涕灭砜威、丁酮威（butocarboxim)、丁酮砜威（butoxycarboxim)、灭多威、戊腈威（nitrilacarb)、草氨酰、噻螨威、抗虫威、硫双卡、久效威 [0025] oxime carbamate salt / ester insecticide: alanycarb, aldicarb, aldicarb sulfoxide Granville, Granville-butanone (butocarboxim), methyl ethyl ketone sulfone Granville (butoxycarboxim), methomyl, valeronitrile Granville (nitrilacarb) , oxamyl, thiophene carbofuran, insect Granville, thiodicarb cards, long effect Granville

[0026] 苯基甲基氨基甲酸盐/酯杀虫剂：除害威、灭害威、丁苯氨酯、丁苯甲氨酯、氯灭杀威、地虫威、敌克鲁威、二氧威、EMPC、杀虫丹、二乙基苯酚甲基氨基甲酸酯、仲丁威、异丙威、 灭虫威、速灭威、兹克威、蜱虱威、猛杀威、残杀威、混杀威、XMC、灭杀威 [0026] phenyl methyl carbamate / ester Pesticides: Pesticides Granville, Granville terminator, styrene-butadiene urethane, butyl benzyl urethane, chlorine kill Granville, Granville ground insect enemy Kelu Wei, Granville dioxide, EMPC, killing Dan, diethyl phenol, methyl carbamate, bassa, isopropyl Granville, methiocarb, MTMC, Zi Kewei, lice ticks Wei, Wei Meng kill, kill Granville, Granville mixed kill, XMC, killing Granville

[0027] 干燥剂杀虫剂：硼酸、硅藻土、硅凝胶 [0027] desiccant insecticides: boric acid, diatomaceous earth, silica gel

[0028] 二酰胺杀虫剂：氯虫酰胺、氰虫酰胺（cyantraniliprole)、氟虫酰胺 [0028] diamide insecticide: chlorantraniliprole, Cyantraniliprole (cyantraniliprole), flubendiamide

[0029] 二硝基酚杀虫剂：消螨酚、硝丙酚、戊硝酚、DNOC [0029] dinitrophenol pesticides: eliminate mites phenol, nitric propofol, amyl nitrate phenol, DNOC

[0030] 氟杀虫剂：氟硅酸钡、冰晶石、氟化钠、氟硅酸钠、氟虫胺 [0030] fluoro-pesticides: fluorine barium silicate, cryolite, sodium fluoride, sodium fluoride, sulfluramid

[0031] 甲脒杀虫剂：阿米曲拉、杀虫脒、伐虫脒、伐派虫脒（formparanate) [0031] formamidine insecticides: Ami Triton, chlorphenamidine, Acetamiprid cutting, cutting school acetamiprid (formparanate)

[0032] 熏蒸杀虫剂：丙烯腈、二硫化碳、四氯化碳、氯仿、氯化苦、对二氯苯、1，2-二氯丙烷、甲酸乙酯、二溴乙稀、二氯乙烧、乙烯氧化物、氰化氢、碘甲烧、溴甲烷、甲基氯仿、二氯甲烷、萘、膦、硫酰氟、四氯乙烷 [0032] insecticide fumigation: acrylonitrile, carbon disulfide, carbon tetrachloride, chloroform, chloropicrin, para-dichlorobenzene, 1,2-dichloropropane, ethyl formate, ethylene-dibromo, dichloro acetic burn , ethylene oxide, hydrogen cyanide, methyl iodide burning, methyl bromide, methyl chloroform, methylene chloride, naphthalene, phosphine, sulfuryl fluoride tetrachloroethane

[0033] 无机杀虫剂：硼砂、硼酸、多硫化钙、油酸铜、硅藻土、氯化亚汞、硫氰酸钾、硅胶、硫氰酸钠、参阅砷杀虫剂、参阅氟杀虫剂 [0033] Inorganic pesticides: borax, boric acid, calcium polysulfide, oleic acid, copper, diatomite, mercury chloride, potassium thiocyanate, silica gel, sodium thiocyanate, refer to pesticides arsenic, fluorine see kill pesticides

[0034] 昆虫生长调节剂 [0034] Insect growth regulators

[0035] 几丁质合成抑制剂：双三氟虫脲、稻虱净、定虫隆、灭蝇胺、除虫脲、氟螨脲、氟虫脲、氟铃脲、氯芬奴隆、氟酰脲、多氟脲、氟幼脲、伏虫隆、杀铃脲 [0035] chitin synthesis inhibitors: dual trifluoroacetic insect urea, buprofezin, chlorfluazuron, cyromazine, diflubenzuron, fluorine mites urea, flufenoxuron, hexaflumuron Fennu Long chlorine, fluorine ureide, multi-fluorouracil, fluorine diflubenzuron, teflubenzuron, triflumuron

[0036] 保幼激素模拟物：保幼醚（epofenonane)、苯氧威、氢化保幼素（hydroprene)、丙诺保幼素（kinoprene)、稀虫酯、啦丙醚、稀虫硫酯 [0036] juvenile hormone mimics: Juvenile ether (epofenonane), fenoxycarb, hydrogenated juvenile hormone (hydroprene), buprenorphine juvenile hormone (kinoprene), dilute methoprene, la-propyl ether, thioester rare insect

[0037] 保幼激素：保幼激素I、保幼激素II、保幼激素III [0037] juvenile hormone: juvenile hormone I, juvenile hormone II, juvenile hormone III

[0038] 蜕皮激素激动剂：环虫酰肼、氯虫酰肼、甲氧虫酰肼、虫酰肼 [0038] molting hormone agonists: ring tebufenozide, chlorine tebufenozide, methoxyfenozide, tebufenozide

[0039] 蜕皮激素：a-蜕皮激素、脱皮甾酮 [0039] ecdysone: a- ecdysone, ecdysterone

[0040] 蜕皮抑制剂：苯虫醚 [0040] molting inhibitors: phenyl ether worm

[0041] 抗保幼激素：抗保幼激素I、抗保幼激素II、抗保幼激素III [0041] anti-juvenile hormone: anti-juvenile hormone I, anti-juvenile hormone II, anti-juvenile hormone III

[0042] 未归类昆虫生长调节剂：环虫腈（dicyclanil) [0042] Uncategorized insect growth regulator: ring fipronil (dicyclanil)

[0043] 沙蚕毒素类似物杀虫剂：杀虫磺、巴丹、杀虫环、杀虫双 [0043] Nereis toxins like pesticides: bensultap, Bataan, insecticidal Central, Dimehypo

[0044] 烟碱类杀虫剂：氟虫酰胺 [0044] Insecticides: flubendiamide

[0045] 硝基胍杀虫剂：噻虫胺、呋虫胺、吡虫啉、噻虫嗪 [0045] nitroguanidine insecticides: clothianidin, dinotefuran, imidacloprid, thiamethoxam

[0046] 硝基亚甲基杀虫剂：稀啶虫胺、硝乙脲噻挫（nithiazine) [0046] nitromethylene Insecticides: Acetamiprid dilute amine, nitro urea thiophene acetic frustration (nithiazine)

[0047] 吡啶甲胺杀虫剂：啶虫脒、吡虫啉、烯啶虫胺、噻虫啉 [0047] pyridine methylamine Pesticides: acetamiprid, imidacloprid, nitenpyram, thiacloprid

[0048] 有机氯杀虫剂：溴代-001\毒杀芬、001'(??'-001')、乙基-000、1〇1(丫-1〇1、立氯化苯）、甲氧氯、五氯酚、TDE [0048] organochlorine pesticides: bromo -001 \ toxaphene, 001 '(??' - 001 '), ethyl -000,1〇1 (Ah -1〇1, lindane), methoxychlor, pentachlorophenol, TDE

[0049] 环戊二烯杀虫剂：艾氏剂、溴杀烯、冰片丹、氯丹、十氯酮、狄氏剂、二羟丙茶碱(dilor)、硫丹（a-硫丹）、异狄氏齐Ij、HE0D、七氯、HHDN、碳氯灵、异艾氏齐I」、氯戊环、灭蚁灵 [0049] cyclopenta pesticides: aldrin, bromine kill ene, borneol Dan, chlordane, chlordecone, dieldrin, dyphylline (dilor), endosulfan (a- endosulfan) , endrin Qi Ij, HE0D, heptachlor, HHDN, carbon chlorine spirit, iso Ehrlich Qi I "chlorine dioxolane, mirex

[0050] 有机磷杀虫剂 [0050] organophosphorus pesticides

[0051] 有机磷酸盐/酯杀虫剂：溴苯烯磷、毒虫畏、丁烯磷、敌敌畏、百治磷、甲基毒虫畏、 福司吡酯、庚稀磷、杀虫乙稀磷（methocrotophos)、速灭磷、久效磷、二溴磷、萘肽磷、磷胺、 丙虫憐、TEPP、杀虫畏 [0051] The organic phosphate / ester insecticide: bromobenzene ene phosphorus, chlorfenvinphos, butene phosphorus, dichlorvos, Dicrotophos, methyl chlorfenvinphos, blessing Secretary topiramate, heptyl dilute phosphorus, phosphorus insecticide ethylene (methocrotophos ), mevinphos, monocrotophos, naled, naphthalene peptide, phosphorus amine, C worm pity, TEPP, insecticidal fear

[0052] 有机硫代磷酸盐/酯杀虫剂：蔬果磷、丁苯硫磷、稻丰散 [0052] The organic thiophosphate / ester insecticide: fruits and vegetables phosphorus, styrene-butadiene parathion, phenthoate

[0053]脂肪族有机硫代磷酸盐/醅杀虫剂:家蝇磷、胺吸磷、硫线磷、氯氣磷、氯甲磷、田乐磷（田乐磷-0、田乐磷-s)、内吸磷（内吸磷-0、内吸磷-s)、甲基内吸磷（内吸磷-O-甲基、内吸磷-S-甲基）、砜吸磷（demeton-S-methylsulphon)、乙拌磷、乙硫磷、灭线磷、IPSP、 异丙磷、马拉硫磷、虫螨畏、亚砜磷、异亚砜磷、砜拌磷、甲拌磷、治螟磷、特丁硫磷、甲基乙拌憐 [0053] aliphatic organic thiophosphate / Grains Pesticides: housefly phosphorus, amine uptake, cadusafos, chlorine phosphorus, chlorine A phosphorus, phosphorus Le Tian (Tian Le -0 phosphorus, phosphorus -s dengaku ), the absorption of phosphorus uptake -0 (inside, the absorption of phosphorus -s), phosphorus uptake uptake -O- methyl (meth Nene, the absorption of phosphorus -S- methyl), oxydemeton (demeton- S-methylsulphon), B disulfoton, ethion, ethoprophos, IPSP, isopropyl phosphorus, malathion, carbofuran fear, sulfoxide phosphorus, phosphorus iso sulfoxide, sulfone disulfoton, phorate, cure borer phosphorus, terbufos, methyl ethyl mixed with pity

[0054] -脂肪酰胺有机硫代磷酸盐/酯杀虫剂：赛果、果虫磷、乐果、益果、安果、灭蚜磷、 氧乐果、发果、苏果、蚜灭多 [0054] - fatty acid amide organic thiophosphate / ester insecticide: Results, fruit worm phosphorus, dimethoate, the benefits of fruit, fruit Ann, Mecarbam, omethoate, send fruit, Su Guo, aphids methomyl

[0055] -有机硫代磷酸肟杀虫剂：氯辛硫磷、辛硫磷、甲基辛硫磷 [0055] - oxime organic phosphorothioate pesticides: phoxim chlorine, phoxim, methyl phoxim

[0056] 杂环有机硫代磷酸盐/醅杀虫剂:甲基吡啶、蝇毒磷、畜虫磷、二恶磷、因毒磷、灭虫牙松、茂果、伏杀硫磷、吡唑硫磷、Ij达嗪硫磷、畜宁磷（quinothion) [0056] heterocyclic organic thiophosphate / Grains Pesticides: picoline, coumaphos, livestock insects phosphorus, phosphorus dioxin, because toxic phosphorus, pest control teeth loose, Mao fruit, phosalone, pyrazole parathion, Ij of triazine parathion, livestock Ning phosphorus (quinothion)

[0057] -苯并硫啦喃有机硫代磷酸盐/酯杀虫剂：苯噻双硫磷（dithicrofos)、苯噻硫磷(thicrofos) [0057] - benzo furans organic sulfur matter thiophosphate / ester insecticide: benzene thiophene temephos (dithicrofos), benzene methidathion (thicrofos)

[0058] -苯并三嗪有机硫代磷酸盐/酯杀虫剂：乙基谷硫磷、甲基谷硫磷 [0058] - benzotriazine organic thiophosphate / ester insecticide: azinphos-ethyl, azinphos-methyl

[0059] -异吲哚有机硫代磷酸盐/酯杀虫剂：氯亚磷、亚胺硫磷 [0059] - isoindole organic thiophosphate / ester insecticide: chlorine phosphorous, phosmet

[0060] -异5恶唑有机硫代磷酸盐/酯杀虫剂：异5恶唑磷、丙硫$慕唑磷（zolaprofos) [0060] - 5-oxazolyl different organic thiophosphate / ester insecticide: iso-5-oxazolyl phosphorus, propylthiouracil $ Mu yl phosphate (zolaprofos)

[0061] -吡挫啼啶有机硫代磷酸盐/酯杀虫剂：灭虫吡啶（chlorprazophos)、定菌磷 [0061] - pyridine frustrated cry pyridine organic thiophosphate / ester insecticide: pest control pyridine (chlorprazophos), gnotobiotic phosphorus

[0062] -吡啶有机硫代磷酸盐/酯杀虫剂：毒死蜱、甲基毒死蜱 [0062] - pyridine organic thiophosphate / ester insecticides: chlorpyrifos, chlorpyrifos-methyl

[0063] -嘧啶有机硫代磷酸盐/酯杀虫剂：丁嘧硫磷、二嗪磷、乙嘧硫磷、丙嘧硫磷、乙基虫螨磷、甲基虫螨磷、乙酰嘧啶磷、嘧啶磷、丁基嘧啶磷 [0063] - pyrimidine organic thiophosphate / ester insecticide: Ding ethyl parathion, diazinon, parathion ethyl acetate, propyl ethyl parathion, pirimiphos-ethyl, pirimiphos methyl, acetyl pirimiphos , pirimiphos, butyl pirimiphos

[0064] -喹喔啉有机硫代磷酸盐/酯杀虫剂：喹硫磷、甲基喹硫磷 [0064] - quinoxaline organic thiophosphate / ester insecticide: quinoline parathion, parathion methyl quinoline

[0065] -噻二唑有机硫代磷酸盐/酯杀虫剂：乙基杀扑磷、噻唑磷、杀扑磷、乙噻唑磷 [0065] - thiadiazole organic dithiophosphate / ester insecticide: ethyl methidathion, fosthiazate, methidathion, B fosthiazate

[0066] -三唑有机硫代磷酸盐/酯杀虫剂：氯唑磷、三唑磷 [0066] - triazole organic thiophosphate / ester insecticide: chlorazol phosphorus, triazophos

[0067]苯基有机硫代磷酸盐/醅杀虫剂:偶氮磷、溴硫磷、乙基溴硫磷、三硫磷、虫螨磷、 杀螟腈、赛灭磷、异氯磷、除线磷、牛津郡丙硫磷（etaphos)、伐灭磷、皮蝇磷、杀螟硫磷、丰索磷、倍硫磷、乙基倍硫磷、速杀硫磷、碘硫磷、倍硫磷亚砜、对硫磷、甲基对硫磷、芬硫磷、对氯硫磷、丙溴磷、低毒硫磷、硫灭克磷、硫甲双磷、皮蝇磷-3、三氯丙氧磷 [0067] phenyl thiophosphate organic / pesticide grains: Even nitrogen and phosphorus, bromine parathion, parathion ethyl bromide, three parathion, pirimiphos, cyanophos, race acephate, iso phosphorus chloride, In addition to fenamiphos, Oxfordshire Prothiophos (etaphos), cutting acephate, Hypoderma phosphorus, fenitrothion, fensulfothion, fenthion, fenthion ethyl, speed kill parathion, parathion iodine, times sulfoxide parathion, parathion, methyl parathion, Finland parathion, parathion chlorine, Profenophos, low toxicity parathion, sulfur ethoprophos, temephos, Hypoderma phosphorus -3, three chlorpromazine phosphorus oxychloride

[0068] 膦酸盐/酯杀虫剂：布托酯、敌百虫 [0068] phosphonate / ester insecticide: Bhutto ester, trichlorfon

[0069] 硫代膦酸盐/酯杀虫剂：甲基灭蚜磷 [0069] thio phosphonate / ester insecticide: methyl Mecarbam

[0070]苯基乙基硫代膦酸盐/醅杀虫剂:地虫磷、壤虫磷 [0070] phenyl ethyl thio phosphonate / Grains Pesticides: fonofos, phosphorus soil insects

[0071]苯基苯基硫代膦酸盐/醅杀虫剂:苯腈磷、EPN、福赐松 [0071] phenyl thio phosphonate / Grains Pesticides: benzonitrile phosphorus, EPN, thanks to loose blessing

[0072] 氨基磷酸盐/酯杀虫剂：育畜磷、苯线磷、伐线丹、二噻磷、棉安磷、甲胺基嘧啶磷(pirimetaphos) [0072] amino phosphate / ester insecticide: educating livestock phosphorus, fenamiphos, cutting red line, two thiophene phosphorus, phosphorus Ann Cotton, methylamino pyrimidine phosphorus (pirimetaphos)

[0073] 硫代磷酰胺（phosphoramidothioate)杀虫剂：乙酰甲胺磷、水胺硫磷杀虫剂、异柳磷、甲基异柳磷、甲胺磷、烯虫磷 [0073] Thioxophosphamide (phosphoramidothioate) pesticides: acephate, Isocarbophos pesticides, isofenphos, methyl isobutyl Liu P, methamidophos, methoprene phosphorus

[0074] 偶磷肼（phosphorodiamide)杀虫剂：甲氟磷、叠氮磷、丙胺氟、八甲磷 [0074] Even phosphorus hydrazine (phosphorodiamide) Pesticides: mefloquine phosphorus, nitrogen and phosphorus stack, propylamine fluorine, phosphorus bajia

[0075] $恶二嗪杀虫剂：茚虫威 [0075] $ oxadiazine insecticide: Indoxacarb

[0076] _^^二唑酮（oxadiazolone)杀虫剂：恶虫酮 [0076] _ ^^ oxadiazole ketone (oxadiazolone) Pesticides: metoxadiazone

[0077] 邻苯二甲酰亚胺杀虫剂：氯亚磷、亚胺硫磷、胺菊酯 [0077] phthalimide insecticides: chlorine phosphorous, phosmet, tetramethrin

[0078] 吡唑杀虫剂：氯虫酰胺、溴氰虫酰胺、敌蝇威、吡螨胺、唑虫酰胺 [0078] pyrazole insecticide: chlorantraniliprole, bromine Cyantraniliprole, Granville enemy flies, tebufenpyrad, azole insect amide

[0079]苯吡唑杀虫剂：乙酰虫腈（acetoprole)、乙虫腈、氟虫腈、吡唑硫磷(pyraclofos)、R比嗪氟虫腈（pyrafluprole)、R比啶氟虫腈（pyriprole)、甲稀氟虫腈(vaniliprole) [0079] phenyl pyrazole insecticides: Fipronil acetyl (acetoprole), ethiprole, fipronil, pyraclofos (pyraclofos), R triazine than fipronil (pyrafluprole), R fipronil of pyridine ( pyriprole), A rare fipronil (vaniliprole)

[0080] 拟除虫菊酯类杀虫剂 [0080] pyrethroids

[0081] 拟除虫菊酯杀虫剂：氟酯菊酯、丙烯菊酯（生物丙烯菊酯）、熏虫菊、联苯菊酯、苄咲稀菊酯（bioethanomethrin)、环戊稀菊酯、乙氰菊酯、氟氯氰菊酯（(6-氟氯氰菊酯）、格林奈（y-格林奈、I格林奈）、氯氰菊酯U-氯氰菊酯、(6-氯氰菊酯、0-氯氰菊酯、 G-氯氰菊酯）、苯醚氰菊酯、溴氰菊酯、四氟甲醚菊酯、苄菊酯、烯炔菊酯、芬氟司林、吡氯氰菊酯、甲氰菊酯、氰戊菊酯（顺式氰戊菊酯）、氟氰菊酯、氟胺氰菊酯（T-氟胺氰菊酯）、 抗虫菊、炔醚菊酯、甲氧卞氟菊酯、氯菊酯（生物氯菊酯、反式氯菊酯）、苯氧司林、丙炔菊酯、丙氟菊酯（profIuthrin)、节氯菊脂、节咲菊酯（生物节咲菊酯、顺式节咲菊酯）、七氟菊酯、甲稀菊酯（terallethrin)、胺菊酯、四溴菊酯、四氟菊酯 [0081] pyrethroid insecticides: acrinathrin, allethrin (Bioallethrin), smoked tetramethrin, bifenthrin, permethrin dilute benzyl Misaki (bioethanomethrin), cyclopentyl dilute permethrin, B cyhalothrin, cyfluthrin ((6-cyfluthrin), Gelin Nai (y- Gelin Nai, I Gelin Nai), cypermethrin U- cypermethrin, (6-cypermethrin, 0 cypermethrin, G- cypermethrin), benzene, ether cyanide-ju ester, deltamethrin, permethrin tetrafluoroethylene ether, benzyl permethrin, empenthrin, fenfluramine Mr Lam, topiramate cypermethrin, fenpropathrin, fenvalerate (esfenvalerate), fluorine cyhalothrin, fluvalinate (T- fluvalinate), insect chrysanthemum, alkyne etofenprox, methoxy Bian fluorine permethrin, permethrin (biological permethrin, permethrin trans) phenoxy Mr Lam, propyne permethrin, C fluorine permethrin (profIuthrin), section permethrin, permethrin section Misaki (Misaki biological section cypermethrin, permethrin cis section Saki), tefluthrin, A dilute permethrin (terallethrin), tetramethrin, tralomethrin, PTFE pyrethroid

[0082] 拟除虫菊醚杀虫剂：依芬普司、三氟醚菊酯、溴氟醚菊酯、普垂菊酯(protrifenbute)、氟娃菊酯 [0082] ether pyrethroid insecticide: by Fenpu Division, trifluoromethyl etofenprox, bromine, fluorine phenothrin, permethrin Poor vertical (protrifenbute), fluorine baby permethrin

[0083] 氨基啼啶（pyrimidinamine)杀虫剂：啼虫胺、啼螨醚（pyrimidifen) [0083] cry amino pyridine (pyrimidinamine) Pesticides: cry insects amines, cry mites ether (pyrimidifen)

[0084] 吡咯杀虫剂：溴虫腈 [0084] pyrrole insecticide: chlorfenapyr

[0085] 特特拉姆酸（tetramicacid)杀虫剂：螺虫乙酯 [0085] Tete Ram acid (tetramicacid) Pesticides: spirotetramat

[0086] 季酮酸杀虫剂：螺甲螨酯 [0086] tetronic pesticides: spiromesifen

[0087] 噻唑杀虫剂：噻虫胺、噻虫嗪 [0087] thiazole insecticides: clothianidin, thiamethoxam

[0088] 噻唑烷杀虫剂：噻螨威、噻虫啉 [0088] thiazolidine pesticides: carbofuran thiophene, thiacloprid

[0089] 硫脲杀虫剂：丁醚脲 [0089] thiourea insecticides: diafenthiuron

[0090] 脲杀虫剂：伏康脲（flucofuron)、苏康脲（sulcofuron)、参见几丁质合成抑制剂 [0090] urea insecticides: V Kang urea (flucofuron), Su Kang urea (sulcofuron), we see chitin synthesis inhibitors

[0091] 未归类杀虫剂：氯生太尔、环烷酸铜、克罗米酚、EXD、抗螨唑、嘧酰虫胺(fenoxacrim)、氟蚁腙（hydramethylnon)、稻痕灵、特螨腈（malonoben)、氰氟虫腙(metaflumizone)、尼氟利地、蚊绳灵、U达螨灵、啶虫丙醚、氟虫吡喹（pyrifluquinazon)、雷复尼特、氟啶虫胺腈（sulfoxaflor)、三苯噻螨吩（triarathene)、唑姐威（triazamate)。 [0091] Uncategorized pesticides: triclosan Blantyre, copper naphthenate, clomiphene, EXD, azole anti-mite, insect acid ethyl amine (fenoxacrim), fluorine ants hydrazone (hydramethylnon), marks rice spirit, special chlorfenapyr (malonoben), metaflumizone (metaflumizone), Nigeria F Lee, the mosquito rope Ling, U of mites, Acetamiprid propyl ether, fipronil Bikui (pyrifluquinazon), rafoxanide, fluorine Acetamiprid amine nitrile (sulfoxaflor), triphenyl thiophene mites thiophene (triarathene), azole sister Wei (triazamate).

[0092] 上述杀虫剂和及其进一步的鉴定和描述的链接可参考http://www.alanwood. net/pesticides/class_insecticides.html，其全文纳入本文。 [0092] link above pesticides and its further identified and described herein may refer to http: //www.alanwood net / pesticides / class_insecticides.html, incorporated herein in its entirety.

[0093] 特别优选的除草剂为草甘膦（C3H8N05P，[(膦酰基甲基）氨基]乙酸， CAS#1071-83-6)。 [0093] Especially preferred herbicide is glyphosate (C3H8N05P, [(phosphonomethyl) amino] acetic acid, CAS # 1071-83-6). 本发明可用的其他除草剂包括： Other herbicides of the present invention can be used include:

[0094] 酰胺类除草剂：草毒死、氨唑草酮、氟丁酰草胺、胺酸杀、苄草胺、溴丁酰草胺、苯酮唑（cafenstrole)、⑶EA、三环塞草胺、二甲噻草胺（二甲噻草胺-p)、草乃敌、三唑磺、艾尼胺（etnipromid)、四唑草胺、氟唑磺隆、氟胺草唑、虎威、海罗胺（halosafen)、草特灵、异恶草胺（isoxaben)、敌草胺、抑草生、稀草胺、炔敌稗、醌萍胺、啼啶聘草醚、特丙胺（tebutam) [0094] amide herbicides: poison grass, ammonia carfentrazone ketone, fluorine butyryl alachlor, histidine kill, benzyl metolachlor, alachlor bromo butyryl, benzophenone azole (cafenstrole), ⑶EA, tricyclic Cypriot grass amine, dimethyl thiophene alachlor (dimethyl thiophene alachlor -p), grass is the enemy, triazole sulfonamide, Aini amine (etnipromid), tetrazole alachlor, flucarbazone, amine fluoride grass yl, Tiger, sea Luo amine (halosafen), grass Trane, isoxaben (isoxaben), napropamide, naptalam, dilute alachlor, alkyne propanil, Ping quinone amine, pyridine employed cry Ethoxyfen, special propylamine (tebutam)

[0095] 苯胺类除草剂：地快乐、落草胺、稗草胺、环草胺除草剂、吡氟草胺、乙氧苯草胺(etobenzanid)、芬纳胺（fenasulam)、氟噻草胺、三吡氟草胺（flufenican)、齒苯胺挫(ipfencarbazone)、苯噻草胺、氟草磺、恶唑酰草胺、杀草利、萘丙胺、蔬草灭、氟吡酰草胺(picolinafen)、敌稗、甲横草胺（sulfentrazone) [0095] aniline herbicides: happy and Luocao amines, barnyard grass amines, cyclic alachlor herbicide diflufenican, ethoxy benzene alachlor (etobenzanid), Fenner amine (fenasulam), flufenacet, three diflufenican (flufenican), tooth aniline frustration (ipfencarbazone), MEFENACET, sulfur fluoride grass, grass oxazole acid amine herbicide Lee, Naproanilide, vegetables off the grass, flurbiprofen acid alachlor (picolinafen) , propanil, A cross alachlor (sulfentrazone)

[0096] 芳基丙氨酸类除草剂：新燕灵、草吡唑（草吡唑-M) [0096] aryl alanine herbicides: new Yan Ling, grasses pyrazole (grass pyrazole -M)

[0097]乙酰氯苯胺类除草剂:乙草胺、甲草胺、去草胺、丁烯草胺、异丁草胺、乙酰甲草胺、 二甲草胺、吡唑草胺（metazachlor)、甲氧毒草安（S-甲氧毒草安）、丙草胺、扑草胺、异丙草胺、广草胺、特丁草胺、甲氧噻草胺、二甲苯草胺（xylachlor) [0097] acetyl chlorobenzene herbicides: acetochlor, alachlor, metolachlor go, butene alachlor, butachlor isopropyl, acetyl alachlor, dimethyl metolachlor, alachlor pyrazole (metazachlor), metolachlor (S- metolachlor), metolachlor, alachlor flutter, Propisochlor wide alachlor, butachlor special, methoxy thiophene alachlor, metolachlor xylene (xylachlor)

[0098] 磺酰苯胺（sulfonanilide)类除草剂:氟草黄、氯酷磺草胺(cloransulam)、双氯磺草胺、双氟磺草胺、唑嘧磺草胺、磺草唑胺、氟草磺胺、嘧磺草胺（pyrimisulfan)、氟唑草胺 [0098] anilide (sulfonanilide) herbicides: yellow grass fluorine, chlorine cool alachlor (cloransulam), diclofenac alachlor, double-fluoro alachlor, azole ethyl alachlor, metosulam, fluorine sulfa grass, grass-ethyl amine (pyrimisulfan), fluorine carfentrazone amine

[0099] 磺酰胺类除草剂：黄草灵、卡巴胺（carbasulam)、双氧威（fenasulam)、黄草消、五氟磺草胺、甲氧磺草胺、参见磺酰脲类除草剂 [0099] sulfonamide herbicide: asulam, Kabbah amine (carbasulam), fenoxycarb (fenasulam), oryzalin, pentafluoroethyl alachlor, pyroxsulam see of sulfonylurea herbicides

[0100] 硫代酰胺类除草剂：酰苯草酮（bencarbazone)、氯硫酰草胺 [0100] thioamide herbicides: benzophenone grass ketone (bencarbazone), thionyl chlorine alachlor

[0101] 抗生素类除草剂：双丙氨膦 [0101] antibiotics, herbicides: bialaphos

[0102] 芳族酸类除草剂： [0102] The aromatic acid herbicides:

[0103] 苯甲酸类除草剂：草灭平、麦草畏、2, 3, 6-TBA、三氯茴香酸 [0103] benzoic acid herbicides: chloramben, dicamba, 2, 3, 6-TBA, trichloro-anisic acid

[0104] 嘧啶羟苯甲酸除草剂:双草醚、嘧草醚 [0104] pyrimidine paraben herbicides: double grass ether, ethyl ether grass

[0105] 嘧啶硫代苯甲酸除草剂:嘧草硫醚 [0105] pyrimidine sulfobenzate herbicides: ethyl sulfide grass

[0106] 邻苯二甲酸除草剂：敌草索 [0106] phthalic acid herbicides: diuron Cable

[0107] 甲基吡啶酸除草剂：氯氨吡啶酸、二氯吡啶酸原、毒莠定 [0107] methylpyridine acid herbicides: aminopyralid, clopyralid original, picloram

[0108] 喹啉羧酸除草剂：二氯喹啉酸、喹草酸 [0108] quinoline carboxylic acid herbicides: quinclorac, quinmerac

[0109] 砷除草剂：二甲胂酸、CMA、DSMA、六氟盐、MAA、MAMA、MSMA、亚砷酸钾、亚砷酸钠 [0109] arsenic herbicides: cacodylate, CMA, DSMA, hexafluoro salt, MAA, MAMA, MSMA, potassium arsenite, sodium arsenite

[0110] 苯甲酰基环己二酮除草剂：甲基磺草酮、磺草酮、磺酰草吡唑、玉米除草剂 [0110] benzoyl cyclohexanedione herbicides: mesotrione, sulcotrione, sulfonyl pyrazole grass, corn herbicide

[0111] 苯并呋喃基烷基磺酸盐/酯除草剂：呋草黄、呋草黄 [0111] benzofuranyl alkylsulfonate / ester herbicides: furosemide yellow grass, yellow grass furosemide

[0112] 苯并噻唑类除草剂：草除灵、噻草隆、噻唑禾草灵、苯噻草胺、噻唑隆 [0112] benzothiazole herbicides: benazolin, diuron thiophene, thiazole diclofop, MEFENACET, thiazole Long

[0113] 氨基甲酸盐/酯类除草剂：黄草灵、卡波灵（carboxazole)、氯脯灵(chlorprocarb)、节胺灵、双氧威（fenasulam)、卡灵草、芽根灵 [0113] The carbamate / herbicides: asulam, Kaposi Ling (carboxazole), chlorine preserved Ling (chlorprocarb), amine Spirit Festival, fenoxycarb (fenasulam), Carling grass shoots Ling root

[0114] 苯基氨基甲酸盐/酯类除草剂：燕麦灵、BCPC、威磺灵（carbasulam)、雷克拉、 CEPC、氯草灵、氯苯胺灵、CPPC、双苯胺灵、棉胺宁、苯敌草、乙基苯敌草、苯胺灵、灭草灵 [0114] phenyl carbamate / herbicides: barban, BCPC, Wei Ling sulfonamide (carbasulam), Carbetamide, CEPC, chlorine grass Ling, chlorpropham, CPPC, double propham, cotton amine Ning, phenmedipham, ethylbenzene diuron, propham, Swep

[0115] 环己稀聘类除草剂：禾草灭、丁苯草酮、稀草酮、克劳普草酮（cloproxydim)、噻草酮、环苯草酮、稀禾定、吡喃草酮、草酮 [0115] cyclohexene employed herbicides: grasses off, styrene-butadiene grass ketone ketone dilute grass, grass Kelao Pu ketone (cloproxydim), thiophene-one grass, grass-one benzene ring, sethoxydim, tepraloxydim grass ketone

[0116] 环丙基异_唑除草剂：氯草酮、异恶唑草酮 [0116] cyclopropyl isopropyl _ azole herbicides: chlorine grass ketone, isoxaflutole

[0117] 二甲酰亚胺类除草剂：剛哚酮草酯、氟奋乃静（flumezin)、氟烯草酸、丙炔氟草胺、炔草胺（flumipropyn)、参见尿啼啶除草剂 [0117] dicarboximide herbicide: just one grass indole ester, fluphenazine (flumezin), fluorine-ene oxalate, veracity and alachlor, metolachlor alkyne (flumipropyn), see the urine cry pyridine herbicide

[0118] 二硝基苯胺除草剂：氟草胺、仲丁灵、挞乃、乙丁烯氟灵、氟消草、异乐灵、甲乐灵(methalpropalin)、磺乐灵、黄草消、二甲戊乐灵、氨氟乐灵、环丙氟灵、氟乐灵 [0118] dinitroaniline herbicides: fluorine alachlor, sec-Ling, is tart, butene-fluoro-ethyl spirit, fluorine eliminate grass, different music spirit, methyl trifluralin (methalpropalin), sulfur trifluralin, oryzalin, pendimethalin, trifluralin ammonia, cyproterone F Ling, trifluralin

[0119] 二硝基酚类除草剂：敌螨通、硝丙酚、二硝戊酚、地乐酚、乐消、DN0C、硝草酚、甲基特乐酯 [0119] dinitrophenols herbicides: mites through enemy, nitro propofol, dinitramide amyl phenol, dinoseb, music consumption, DN0C, pendimethalin phenol, methyl ester Kitt music

[0120] 二苯醚除草剂：氯氟草醚 [0120] diphenyl ether herbicides: Cellulose ether

[0121] 硝基苯醚除草剂：氟锁草醚、苯草醚、治草醚、甲氧除草醚、草枯醚、艾尼胺（etnipromid)、消草醚、乙羧氟草醚、氟除草醚、氟磺胺草醚、氟呋草醚、海罗胺(halosafen)、乳氟禾草灵、除草醚、三氟甲草醚、乙氧氟草醚 [0121] nitrobenzene ether herbicides: acifluorfen, aclonifen, Bifenox, methoxy nitrofen, CNP, Aini amine (etnipromid), eliminate grass ether, ethyl fluoroglycofen, fluorine nitrofen, fomesafen, fluorine furosemide grass ether, Jairo amine (halosafen), lactofen, nitrofen, trifluoromethanesulfonic grass ether, oxyfluorfen

[0122] 二硫代氨基甲酸盐/酯类除草剂：棉隆、威百亩 [0122] dithio carbamate / herbicides: dazomet, metam sodium

[0123]卤代脂族（halogenatedaliphatic)除草剂：阿罗酸（alorac)、茅滴混剂、茅草枯、氟丙酸、六氯丙酮、碘甲烷、溴甲烷、氯乙酸、SMA、TCA [0123] halogenated aliphatic (halogenatedaliphatic) herbicides: Arrow acid (alorac), Mao drops Mixture, dry grass, fluorine acid, six chlorine acetone, methyl iodide, methyl bromide, monochloroacetic acid, SMA, TCA

[0124] 咪唑啉酮类除草剂：咪草酸、甲氧咪草烟、甲基咪草烟、咪唑烟酸、灭草喹、咪唑乙烟酸 [0124] imidazolinone herbicides: Mi oxalic acid, imazamox, imazethapyr methyl, imazapyr, imazaquin, imazethapyr

[0125] 无机除草剂：氨基磺酸铵、硼砂、钙氯酸盐、硫酸铜、硫酸亚铁、钾重氮化合物、氰酸钾、叠氮化钠、氯酸钠、硫酸 [0125] Inorganic herbicides: ammonium sulfamate, borax, calcium chlorate, copper sulfate, ferrous sulfate, diazo compound, potassium, potassium cyanate, sodium azide, sodium chlorate, sulfuric acid

[0126] 腈除草剂：溴波尼（bromobonil)、溴苯腈、羟敌草腈、敌草腈、碘波尼(iodobonil)、碘苯腈、双唑草腈 [0126] Nitrile herbicide: bromine Pawnee (bromobonil), bromoxynil, hydroxyl nitrile diuron, diuron nitrile, iodine Pawnee (iodobonil), ioxynil, double carfentrazone nitrile

[0127] 有机磷除草剂：甲基胺草磷、莎稗磷、地散磷、双丙氨膦、丁胺磷、2、4_DEP、DMPA、 EBEP、杀木磷、草铵膦（草铵膦-P)、草甘膦、哌草磷P恶二唑酮类除草剂：恶唑隆、灭草定、稻思达、恶草酮 [0127] organophosphorus herbicides: methylamine phosphorus grass, anilofos, Bensulide, bialaphos, butylamine phosphorus, 2,4_DEP, DMPA, EBEP, kill wood phosphorus, glufosinate (glufosinate -P), glyphosate, piperazine grass phosphorus P oxadiazole herbicide: Long oxazole, methazole, rice Sida, oxadiazon

[0128] 巧恶唑类除草剂：异$恶甲草威、异•苯砜、异恶隆、异恶草胺、氯草酮、异恶唑草酮、单甲异5隆、皮罗威（pyroxasulfone)、托普拉威（topramezone) [0128] Qiao oxazole herbicides: iso $ alachlor evil Granville, iso • benzene sulfone, isoxazolyl Long, isoxaben, chlorine grass ketone, isoxaflutole, a single methyl isobutyl 5 Long, Pi Luowei (pyroxasulfone), Top Rahway (topramezone)

[0129] 含苯氧除草剂：杀草全、稗草胺、2, 4-DEB、2, 4-DEP、戊味禾草灵、滴硫钠、抑草蓬、 艾特尼普拉米（etnipromid)、芬特拉扣（fenteracol)、垂伏普斯（trifopsime) [0129] containing phenoxy herbicides: Full herbicide, barnyard grass amine, 2, 4-DEB, 2, 4-DEP, amyl taste diclofop, sodium sulfur droplets, inhibiting grass Peng, Ait Neptune Lamy ( etnipromid), Fen Tela deduction (fenteracol), vertical volt Phillips (trifopsime)

[0130] 苯氧基乙酸类除草剂：4-CPA、2, 4-D、3, 4-DA、MCPA、MCPA-硫代乙酯、2, 4, 5-T [0130] phenoxyacetic acid herbicides: 4-CPA, 2, 4-D, 3, 4-DA, MCPA, MCPA- thio, ethyl, 2, 4, 5-T

[0131]苯氧基丁酸类除草剂：4-CPB、2, 4-DB、3, 4-DB、MCPB、2, 4, 5-TB [0131] phenoxybutyric acid herbicides: 4-CPB, 2, 4-DB, 3, 4-DB, MCPB, 2, 4, 5-TB

[0132] 苯氧基丙酸类除草剂：调果酸、4-CPP、2,4-滴丙酸（2,4-滴丙酸-?)、3,4-0卩、 2, 4, 5-涕丙酸、甲氯丙酸、（甲氯丙酸-P) [0132] phenoxy acid herbicides: tune acid, 4-CPP, 2,4- drop acid (? Dichlorprop -), 3,4-0 Jie, 2, 4, 5- tears acid, chlorine acid methyl (meth chlorine acid -P)

[0133] 芳氧基苯氧基丙酸类除草剂：炔禾灵（chlorazifop)、炔草酸、2-(4-(4-氯苯氧基）苯氧基）丙酸、氰氟草酯、禾草灵、恶唑禾草灵、（恶唑禾草灵-P)、噻唑禾草灵、 吡氟禾草灵、（吡氟禾草灵-P)、吡氟氯禾灵、（吡氟氯禾灵-P)、异恶草醚、恶唑酰草胺(metamifop)、喔草酯、喹禾灵、（喹禾灵-P)、垂伏普（trifop) [0133] aryloxy phenoxy acid herbicides: alkyne Wo Ling (chlorazifop), clodinafop, 2- (4- (4-chlorophenoxy) phenoxy) propionic acid, cyhalofop, diclofop, fenoxaprop, (fenoxaprop -P), thiazole diclofop, fluazifop, (fluazifop -P), haloxyfop, (topiramate fluoride chlorine Wo Ling -P), different evil grass ether, oxazole acid alachlor (metamifop), propaquizafop, quizalofop, (quizalofop -P), vertical V P (trifop)

[0134] 苯二胺类除草剂：敌乐胺、氨氟乐灵 [0134] terephthalic herbicide: Music enemy amines, ammonia trifluralin

[0135] 吡唑类除草剂：四唑嘧磺隆、野燕枯、氟吡嘧磺隆、吡草胺、环醚吡嘧磺隆、吡嘧磺隆、皮罗威（pyroxasulfone) [0135] pyrazole herbicides: ethyl tetrazole, difenzoquat, flurbiprofen ethyl, metazachlor, cyclic ether-ethyl pyridine, ethyl pyridine, Piluo Wei (pyroxasulfone)

[0136] 苯酰吡唑类除草剂：吡草酮、磺酰草吡唑、吡唑特、苄草唑、苯唑草酮 [0136] benzoyl pyrazole herbicides: topiramate ketone grass, grass sulfonyl pyrazole, pyrazole special, benzyl azole grass, grass ketone oxacillin

[0137] 苯基吡唑类除草剂：异丙吡草酯、吡氯草胺、唑啉草酯、吡草醚 [0137] phenylpyrazole herbicides: isopropyl ester grass topiramate, topiramate chlorine alachlor, pinoxaden, pyraflufen

[0138] 哒嗪类除草剂：哒草醚、哒草醇（pyridafol)、哒草特 [0138] pyridazine herbicides: pyridate ether, pyridate alcohol (pyridafol), pyridate

[0139] 哒嗪酮类除草剂：溴杀草敏、氯草敏、草哒酮、哒嗪氟草酯（flufenpyr)、二甲哒草伏、达草灭、草哒松、哒嗪酮乙酸 [0139] pyridazine herbicides: herbicide-sensitive bromine, chlorine-sensitive grass, grass da ketone, pyridazine fluroxypyr ester (flufenpyr), dimethyl norflurazon, up off the grass, pine grass da pyridazinone acetic acid

[0140] 吡啶类除草剂：氯氨基吡啶酸、一氯吡啶酯、二氯吡啶酸原、吡氟草胺、氟硫草定、 三吡氟草胺（flufenican)、氟草烟、氟啶草、毒莠定、氟吡酰草胺、氯草定、啶磺草胺、噻唑烟酸、绿草定 [0140] pyridine herbicides: aminopyralid acid, a chloro pyridine esters, clopyralid original, diflufenican, dithiopyr three diflufenican (flufenican), fluroxypyr, haloxydine picloram, flurbiprofen acid alachlor, chlorine grass set, alachlor pyridine, thiazole acid, triclopyr

[0141] 啼啶二胺类除草剂：氯胺草啶碱（iprymidam)、硫胺草啶碱（tioclorim) [0141] pyridine sings two herbicides: chloramine grass pyridine base (iprymidam), thiamine grass pyridine base (tioclorim)

[0142] 季铵除草剂：牧草快、1，1-二[2_(二乙基氨基）-2_氧代乙基]-4, 4-联吡啶(diethamquat)、野燕枯、敌草快、伐草快、百草枯 [0142] quaternary ammonium herbicides: Forage fast, 1,1-bis [2_ (diethylamino) -2_ oxoethyl] 4,4-bipyridine (diethamquat), difenzoquat, diquat , cutting paraquat paraquat

[0143]硫代氨基甲酸盐/酯类除草剂：苏达灭除草剂、草灭特、燕麦敌、EPTC、禾草畏、抑草威、异普林特（isopolinate)、甲禾草丹（methiobencarb)、草达灭、坪草丹、克草猛、节草丹、稗草畏、草克死、禾草丹、仲草丹、野麦威、灭草猛 [0143] dithiocarbamates / herbicides: Minnesota eliminate herbicides, especially off the grass, oat enemy, EPTC, fear grass, weed suppression Granville, iso Sprint (isopolinate), A grass Dan (methiobencarb), molinate, Dan Ping grass, g grass fierce, section Caodan, fear barnyard grass, grass grams dead, grass Dan, Dan Chung grass, wild Maiwei, herbicides Meng

[0144] 硫代碳酸盐类除草剂：草灭散、EXD、扑灭生 [0144] thiocarbonate herbicides: grass off loose, EXD, Health Fight

[0145] 硫脲类除草剂：灭草恒 [0145] thiourea herbicides: Herbicides Heng

[0146] 三嗪类除草剂：杀草净、茚磺隆（indaziflam)、吡嘧磺隆、三羟基三嗪(trihydroxytriazine) [0146] triazine herbicides: herbicide net, indene Metsulfuron (indaziflam), topiramate ethyl, trihydroxy-triazine (trihydroxytriazine)

[0147] 氯三嗪类除草剂：阿特拉津、可乐津、草净津、环草津、艾格林津（eglinazine)、草怕津、灭莠津（mesoprazine)、普赛津（procyazine)、甘扑津、扑灭津、另丁津、西玛津、特丁津、草达津 [0147] chlorine triazine herbicides: atrazine, cola Tianjin, cyanazine, ring Kusatsu, Eglin Jin (eglinazine), grass afraid Tianjin, Tianjin destroy atrazine (mesoprazine), Phouesay Jin (procyazine), Gan flutter Tianjin, Tianjin extinguished, another Ding Jin, simazine, terbuthylazine, trietazine

[0148] 甲氧基三嗪类除草剂：阿特拉通、醚草通、扑灭通、密草通、西玛通、甲氧去草净 [0148] methoxy triazine herbicides: atrazine through the ether through the grass, put out pass, through dense grass, Sima Tong, methoxy Terbutryn

[0149] 甲硫基三嗪类除草剂：莠灭净、叠氮净（aziprotryne)、氰草净、敌草净、异戊乙净、盖草津、扑草净、西草净、去草净 [0149] methylthio triazine herbicides: ametryn azide net (aziprotryne), cyanide grass net, net diuron, amyl acetate, net, cover Kusatsu, Prometryne, simetryne, Terbutryn

[0150] 三嗪酮除草剂：胺嗪酮（ametridione)、胺嗪草酮（amibuzin)、环嗪酮、丁嗪草酮、 苯嗪草酮、赛克津 [0150] triazine herbicides: amine hydrochloride trihydrate (ametridione), amine metribuzin (amibuzin), Hexazinone, Ding metribuzin, metamitron, metribuzin

[0151] 三唑类除草剂：杀草强、苯酮唑、三唑磺、氟胺草唑 [0151] triazole herbicides: amitrole, benzophenone, triazole sulfonamide, amine fluoride grass azole

[0152]三唑酮类除草剂：氨唑草酮、酰苯草酮（bencarbazone)、唑酮草酯、氟酮磺隆、齒苯胺挫（ipfencarbazone)、丙苯横隆、甲横草胺、酮横吩酸（thiencarbazone) [0152] triadimefon herbicides: ammonia carfentrazone ketone, benzophenone grass ketone (bencarbazone), trazodone mexyl, flucarbazone teeth aniline frustration (ipfencarbazone), propylbenzene cross Long, A cross alachlor, one cross-thiophene acid (thiencarbazone)

[0153] 三唑嘧啶类除草剂：氯酯磺草胺（cl〇ransulam)、双氯磺草胺、双氟磺草胺、唑嘧磺草胺、磺草唑胺、五氟磺草胺、甲氧磺草胺 [0153] triazolopyrimidine herbicides: chlorine esters alachlor (cl〇ransulam), diclofenac alachlor, double-fluoro alachlor, azole ethyl alachlor, metosulam, pentafluoroethyl alachlor, pyroxsulam

[0154] 尿啼啶类除草剂：双苯啼草酮、除草定、氟丙啼草酯、丙啼草酯（flupropacil)、异草定、环草定、嘧啶肟草醚、特草定 [0154] Urine cry pyridine herbicides: Diphenyl ketone cry grass, bromacil, fluorine propionate ester grass cry, cry grass propyl ester (flupropacil), Yi Cao set, ring set grass, saflufenacil, particularly given the grass

[0155] 尿素类除草剂：噻草隆、苄草隆、环莠隆、氯双脲、氟吡草腙、异草完隆、异恶隆、噻唑隆、单甲异,隆、草完隆 [0155] urea herbicides: diuron thiophene, benzyl diuron, atrazine ring Long, chlorine diurea, diflufenzopyr, Yi Cao End Long, Long isoxazolyl, thiazolyl Long, methyl isobutyl single, long, long after the grass

[0156] 苯基脲类除草剂：安尼隆（anisuron)、播土隆、氯溴隆、赤罗隆（chloreturon)、绿麦隆、枯草隆、杀草隆、枯莠隆、恶唑隆、敌草隆、非草隆、伏草隆、伏罗隆（fluothiuron)、异丙隆、利谷隆、灭草恒、甲基杀草隆、吡喃隆、秀谷隆、甲氧隆、绿谷隆、灭草隆、草不隆、对氟隆（parafluron)、稀草隆、环草隆、四氟隆、噻苯隆 [0156] phenyl urea herbicides: Anni Long (anisuron), sowing soil Long, chloro bromo-long, red Luolong (chloreturon), chlorotoluron, B. Long, Daimuron, dry herbicides Long, Long oxazole diuron, non diuron, fluometuron, V Luolong (fluothiuron), isoproturon, linuron herbicides constant, methyl Daimuron, pyran Long, Long Valley show, methoxy Long, Long Green Valley, herbicides Long, long grass on Freon (parafluron), dilute diuron, diuron ring, PTFE Long, thidiazuron

[0157] 磺脲类除草剂： [0157] sulfonylurea herbicides:

[0158] 嘧啶基磺酰脲类除草剂:酰嘧磺降、四晔嘧磺降、苄嘧磺降、氯嘧磺降、环丙嘧磺隆、乙氧嘧磺隆、啶嘧磺隆、氟吡磺隆、氟啶嘧磺隆、比甲酰胺磺隆、氟吡嘧磺隆、 P坐P比啼磺隆、甲基二磺隆、环醚吡啼磺隆（metazosulfuron)、烟啼磺隆、啼苯胺磺隆(orthosulfamuron)、环氧啼磺隆、氟啼磺隆、丙啼磺隆（propyrisulfuron)、啦啼磺隆、砜啼磺隆、甲嘧磺隆、将磺酰磺隆、三氟啶磺隆 [0158] pyrimidinyl sulfonylurea herbicides: acid ethyl drop four Ye ethyl drop down bensulfuron, chlorimuron drop cyproterone ethyl, ethoxy ethyl, ethyl pyridine, flurbiprofen metsulfuron, fluazinam ethyl, Bijia amide metsulfuron, flurbiprofen ethyl, P P ratio cry sit metsulfuron methyl metsulfuron two cyclic ether topiramate cry metsulfuron (metazosulfuron), sulfur smoke cry Long, Long sings aniline sulfonamide (orthosulfamuron), epoxy Metsulfuron cry, cry Metsulfuron fluorine, propionic cry Metsulfuron (propyrisulfuron), it Metsulfuron cry, cry Metsulfuron sulfone, methyl ethyl will sulfosulfuron, trifloxysulfuron

[0159]三嗪磺酰脲类除草剂:氯磺降、醚磺降、胺苯磺降、碘磺降(iodosulfuron)、甲磺隆、氟磺隆、噻吩磺隆、醚苯磺隆、苯磺隆、氟胺磺隆、三氟甲磺隆 [0159] triazine sulfonylurea herbicides: chlorosulfonic drop, drop ether sulfonate, amine benzenesulfonamide drop, drop of iodine sulfur (iodosulfuron), metsulfuron, prosulfuron, thifensulfuron, triasulfuron, benzene metsulfuron, metsulfuron amine fluoride, trifluoromethanesulfonic Long

[0160] 噻二唑脲类除草剂：丁黄隆、磺噻隆、丁噻隆、噻氟隆、噻苯隆 [0160] thiadiazole herbicides: Dinghuang Long, Long thiophene sulfur, tebuthiuron, thiophene Freon, thidiazuron

[0161] 未归类除草剂：丙烯醛、烯丙醇、环丙嘧啶酸、唑啶草酮、噻草平、苯并双环酮、 二环吡草酮（bicyclopyrone)、丁硫咪唑酮、氰氨化|丐、卡姆本帝（cambendichlor)、伐草克、燕麦酯（chlorfenprop)、氟咪杀、整形醇、环庚草醚、异恶草酮、CPMF、甲酚、青氨、邻二氯苯、哌草丹、草藻灭、唑啶草、氟啶酮、氟略草酮（flurochloridone)、咲草酮、嗪草酸甲酯、茚草酮、甲基异硫氰酸甲酯、0CH、去稗安、五氯酚、戊基恶唑酮、硝酸苯汞醋酸盐、甲硫磺乐灵、嘧啶肟草醚、环酯草醚、灭藻醌、硫氰苯胺、撒力卡品（sulglycapin)、噻二唑草胺(thidiazimin)、灭草环、三甲隆、垂普品丹（tripropindan)、草达克。 [0161] Uncategorized herbicides: acrolein, allyl alcohol, cyproterone pyrimidine acid, azole ketone pyridine grass, grass flat thiophene, benzo-bicyclic ketone, topiramate grass bicyclic ketone (bicyclopyrone), Ding sulfur imidazole ketone, Cyanamid of | beggar, Cam present Emperor (cambendichlor), cutting grass grams of oat ester (chlorfenprop), fluorine kill microphone, plastic alcohol, cycloheptyl grass ether, clomazone, CPMF, cresol, cyanamide, o-dichlorobenzene benzene, dimepiperate, algae off the grass, grass yl pyridine, fluridone, fluorine little grass ketone (flurochloridone), Misaki grass ketone, methyl piperazine grass, indanofan, methyl methyl isothiocyanate, 0CH, Ann went barnyard, pentachlorophenol, amyl oxazolone, phenyl mercuric nitrate acetate, methyl sulfur trifluralin, saflufenacil, pyriftalid, algae hydroquinone, thiocyanate aniline, spread of the card products (sulglycapin ), thiadiazole alachlor (thidiazimin), herbicides ring, three long, hanging Dan Pu products (tripropindan), Dark grass.

[0162] 上述除草剂和进一步鉴定和描述除草剂的链接，可参考http://www.alanwood. net/pesticides/class_herbicides.html，其全文纳入本文。 [0162] said herbicides and herbicide links further identification and description, reference http:. //www.alanwood Net / pesticides / class_herbicides.html, incorporated herein in its entirety.

[0163] 在许多情况下，优选具有两性或阳性表面电荷的农药。 [0163] In many cases, the pesticide preferably has a positive or amphoteric surface charge. 该表面电荷特征可为所用农药所固有，或通过将合适的阳离子或两性离子表面活性剂应用于农药颗粒的表面而获得。 The surface charge characteristics can be obtained by a suitable cationic or zwitterionic surfactants applied to the surface of the pesticide granules obtained inherent in pesticide use, or. 通常，基于总组合物中农药部分的总重（以100重量％计），表面活性剂的用量水平约为0• 01-10重量％ (优选约0• 1-3重量％ )。 In general, based on the total weight of the total composition of pesticide section (to 100% by weight), the amount of surfactant level of about 0 • 01-10% by weight (preferably from about 0 • 1-3 wt.%).

[0164] 合适的阳离子表面活性剂包括：二二十烷基二甲基氯化铵；二二十二烷基二甲基氯化铵；二（十八烷基（dioctadecyidimethyl))二甲基氯化铵；二（十八烷基）二甲基甲磺酸铵；二（十四烷基）二甲基氯化铵和上述脂肪基团的天然产生的混合物，例如，二（氢化动物脂）二甲基氯化铵；二（氢化动物脂）二甲基甲磺酸铵（metho-sulphate);二动物脂二甲基氯化铵；二油烯基二甲基（dioleyidimethyl)氯化铵。 [0164] Suitable cationic surfactants include: twenties two alkyl dimethyl ammonium chloride; two behenyl dimethyl ammonium chloride; di (octadecyl (dioctadecyidimethyl)) dimethylchlorosilane ammonium; di (octadecyl) dimethyl ammonium sulfonate; a mixture of di (tetradecyl) dimethyl ammonium chloride and said aliphatic group of naturally occurring, for example, di (hydrogenated tallow) dimethyl ammonium chloride; di (hydrogenated tallow) dimethyl ammonium sulfamate (metho-sulphate); ditallow dimethyl ammonium chloride; dioleyl dimethyl (dioleyidimethyl) ammonium chloride.

[0165] 这些阳性表面活性剂也包括咪唑啉化合物，例如1-甲基-1-(动物脂基酰胺基_)乙基-2-动物脂基4,5_二氢甲磺酸咪唑啉餐會和1-甲基-1-(棕榈酰基酰胺基） 乙基-2-十八烷基4, 5-二氢甲磺酸咪唑啉鑛'。 [0165] These positive surfactants also include imidazoline compounds, such as 1-methyl-1- (tallow amido _) ethyl-2-tallow imidazoline 4,5_ dihydro mesylate meal and will methyl-1- (palmitoyl-amido) ethyl-2-octadecyl-4, 5-dihydro-imidazolinium methanesulfonate mine '. 其他有用的咪唑啉鐵,材料为2-十七烷基-1-甲基-1 (2-硬脂酰胺基）-乙基-甲磺酸咪唑啉鑛•和2-十二烷基-1-羟乙基-1-油烯基-氯化咪唑啉鐵 Other useful imidazolinium iron material 2-heptadecyl-1-methyl-1 (2- stearamide yl) - ethyl - A mineral acid imidazoline and 2-dodecyl -1 • - -1- hydroxyethyl oleyl - iron chloride imidazoline

[0166] 其他合适阳性表面活性剂的示例包括：二烷基（C12-C22)二甲基氯化铵；烷基(椰油）二甲基苄基氯化铵；十八胺乙酸盐；十四胺乙酸盐；动物脂烷基丙二胺乙酸盐； 十八烷基三甲基氯化铵；烷基（动物脂）三甲基氯化铵；十二烷基三甲基氯化铵；烷基（椰油）三甲基氯化铵；十六烷基三甲基氯化铵；联苯基三甲基氯化铵，烷基（动物脂）咪唑啉季盐；十四烷基甲基苄基氯化铵；十八烷基二甲基苄基氯化铵；二油烯基二甲基氯化铵；聚氧乙烯十二烷基一甲基氯化铵；聚氧乙烯烷基（C12-C22)苄基氯化铵；聚氧乙烯十二烷基一甲基氯化铵；1-羟乙基-2-烷基（动物脂）_咪唑啉季盐；和具有硅氧烷基团作为疏水基团的硅酮阳性表面活性剂，具有氟烷基基团作为疏水基团的含氟阳离子表面活性剂。 [0166] Other suitable surfactants positive examples include: dialkyl (C12-C22) dimethyl ammonium chloride; alkyl (coconut) dimethyl benzyl ammonium chloride; octadecylamine acetate; tetradecylamine acetate; tallow alkyl propylene diamine acetate; octadecyl trimethyl ammonium chloride; alkyl (tallow) trimethylammonium chloride; dodecyltrimethylammonium chloro ammonium; alkyl (coconut) trimethylammonium chloride; cetyl trimethyl ammonium chloride; biphenylyl trimethyl ammonium chloride, alkyl (tallow) imidazoline quaternary salt; fourteen alkyl dimethyl benzyl ammonium chloride; stearyl dimethyl benzyl ammonium chloride; dioleyl dimethylammonium chloride; polyoxyethylene lauryl monomethyl ammonium chloride; polyoxyethylene polyoxyethylene alkyl (C12-C22) benzyl ammonium chloride; polyoxyethylene lauryl monomethyl ammonium chloride; 1- hydroxyethyl-2-alkyl (tallow) imidazoline quaternary salt _; and having siloxane group as the hydrophobic group of positive silicone surfactant having a fluoroalkyl group as the hydrophobic group of the fluorine-containing cationic surfactants.

[0167] 两性（两性离子）表面活性剂在酸性或碱性介质中在分子的亲水部分具有阳性、阴性、或两种电荷。 [0167] amphoteric (zwitterionic) surfactants in acidic or alkaline medium having a positive, negative, or both charges in the hydrophilic part of the molecule. 可以使用任意合适的两性表面活性剂。 You can use any suitable amphoteric surfactants. 例如可使用氨丙酸盐(aminoproprionate)，其中所述氨丙酸盐的烷基链优选约C. 4和约C. 12且可为支链或直链。 For example using ammonia propionate (aminoproprionate), wherein the alkyl chain ammonium propionate is preferably from about about C. 12 C. 4 and may be branched or straight chain. 所述氨丙酸盐也可以是烷基氨丙酸钠。 The ammonia may be propionates alkylamino propionate. 市售代表产品以商品名MIRATAINEJC-HA销售。 Representative products marketed under the trade name MIRATAINEJC-HA sales.

[0168] 其他合适的两性表面活性剂包括，二丙酸盐例如MirataineH2C-HA、磺基甜菜碱(sultaines)例如MirataineASC、甜菜喊例如MirataineBET-0-30、氧化胺例如Barlox 12i和醋酸盐形式的两性咪唑啉衍生物MiranoIJEMConc、二丙酸盐形式的Mirano1 C2M-SFCone.)、和磺酸盐如MiranolJSConc. 〇 [0168] Other suitable amphoteric surfactants include, for example dipropionate MirataineH2C-HA, sulfobetaines (sultaines), for example MirataineASC, such as beet shout MirataineBET-0-30, and amine oxides such as Barlox 12i acetate form amphoteric imidazoline derivatives MiranoIJEMConc, dipropionate form Mirano1 C2M-SFCone.), and sulfonates such as MiranolJSConc. billion

[0169] 两性表面活性剂的其他示例包括氨基酸、甜菜碱、磺基甜菜碱、磺酸甜菜碱(sulfobetaines)、脂肪酸的羧酸盐和磺酸盐、磷酸甜菜碱、咪唑鐵：衍生物、大豆磷脂、蛋黄卵磷脂，下列碱金属盐、碱土金属盐、铵盐或取代的铵盐：烷基两性羧基甘氨酸盐和烷基两性羧基丙酸盐、烷基两性二丙酸盐、烷基两性二乙酸盐、烷基两性甘氨酸盐和烷基两性丙酸盐，其中烷基代表具有6-20碳原子的烷基基团；具有12-18个碳原子的烷基亚氨基丙酸盐、 烷基亚氨基二丙酸盐和烷基两性丙基磺酸盐；烷基甜菜碱和酰氨基丙基甜菜碱和烷基磺基甜菜碱和烷基酰氨基丙基羟基磺酸甜菜碱，其中烷基代表具有6-20碳原子的烷基基团。 [0169] Other examples of amphoteric surfactants include amino acid, betaine, sulfo betaine, betaine sulfonate (sulfobetaines), fatty carboxylates and sulfonates, phosphate betaines, imidazole iron: derivatives, soybean phospholipids, egg yolk lecithin, the following alkali metal salts, alkaline earth metal, ammonium or substituted ammonium salts of: alkyl glycinate amphoteric carboxyl and carboxyl alkyl amphoteric propionates, alkylamphoacetates dipropionate, alkyl amphodicarboxylic acetates, alkyl amphoteric glycinates and alkyl amphopropionates wherein alkyl represents an alkyl group having 6-20 carbon atoms; alkyl imino propionate having 12 to 18 carbon atoms, an alkoxy imino dipropionate and gender propyl alkyl sulfonate; alkyl betaines and amidopropyl betaines and alkyl sultaines and alkyl amidopropyl betaine hydroxy acid, wherein the alkyl group represents an alkyl group having 6-20 carbon atoms.

[0170] 如上所述，本发明的共聚物包括相应量的衣康酸和马来酸部分。 [0170] As described above, the copolymer of the present invention include a corresponding amount of itaconic acid and maleic acid moieties. 这些共聚物可以酸形式存在，作为部分盐或饱和盐。 These copolymers can be acid form, as part of a salt or a saturated salt. 使用盐时，几乎可用任何所需的阳离子物质形成该盐， 具体的是碱金属和碱土金属如钠、钾或钙盐。 When using the salt used in almost any desired material forming the cationic salts, in particular alkali metal and alkaline earth metals such as sodium, potassium or calcium salts.

[0171] 本发明的共聚物如美国专利号第6, 515, 090和6, 706, 837号所述，二者通过引用完全和完整地纳入本文，特别应用了所述'837专利的操作实施例。 [0171] copolymer of the invention as described in U.S. Patent No. 6, 515, 090 and 6, 706, the number 837, both by reference in its entirety and fully incorporated herein, in particular the application of the '837 patent procedure was carried out example. 通常，所述共聚物应所需地包含约10-90重量％的马来酸部分（优选约25-75 %重量），和相应的约90-10重量％ 的衣康酸部分（优选约75-25重量％ )。 Typically, the copolymer should desirably contain about 10-90% by weight of a maleic acid moiety (preferably about 25-75% by weight), and corresponding to about 90-10% by weight of itaconic acid portion (preferably about 75 -25% by weight). 此类中特别优选的一种共聚物为美国密苏里州的贝尔顿市（Belton，M0)专业肥料产品有限公司（SpecialtyFertilizerProducts，LLC)以商标AVAIL®所售的共聚物，其为衣康酸和马来酸酐的部分基本等摩尔量的40重量％固体水性共聚物分散剂，用钠离子进行部分中和（CAS#556055-76-6)，pH值为6-8。 Such particularly preferred is a copolymer of Belton, Missouri City (Belton, M0) sold under the trademark AVAIL® copolymers specialty fertilizer products Limited (SpecialtyFertilizerProducts, LLC), which is itaconic acid and horses anhydride portion substantially equimolar amount of 40% by weight solids aqueous copolymer dispersant, the sodium ions with partially neutralized (CAS # 556055-76-6), pH value of 6-8.

[0172] 本发明的农药组合物中的共聚物含量可在很宽的范围内不同，且主要考虑之一是共聚物的成本。 [0172] copolymer content of the pesticidal composition of the present invention may be in a wide range of different and one of the main consideration is the cost of the copolymer. 通常，基于所述农药组合物总重量（以1〇〇重量％计），所述共聚物应以0.05-10重量％的水平存在（优选0. 1-4重量％，且最优选0.2-2重量％ )。 Typically, (1〇〇% in weight), the copolymer should be present at a level from 0.05 to 10% by weight of the pesticide composition based on the total weight (preferably 1-4 wt%, 0.1, and most preferably from 0.2 to 2 % by weight).

[0173] 所述共聚物优选以部分盐或饱和盐的形式使用。 [0173] The copolymer is preferably used in the form of a salt or partial salt saturated. 这通过添加碱性材料如氢氧化钠或氢氧化钙以产生约5-9、优选约6-8的pH而形成。 This is done by adding an alkaline material such as sodium hydroxide or calcium hydroxide to generate about 5-9, preferably about pH 6-8 is formed. 也可用较低pH酸性或部分盐的共聚物，特别是对于选定单体比率和农药而言。 Acidic or lower pH can also be part of a copolymer of a salt, especially for the selected monomers and the ratio in terms of pesticides. 通常，所述pH应为约2-8。 Typically, the pH should be about 2-8.

[0174] 仅含非常少量的共聚物佐剂的本发明农药组合物可以以与所述无佐剂的标准农药产品相同的水平使用。 [0174] copolymer containing only a very small amount of pesticide adjuvant compositions of the present invention may be the non-adjuvanted standard pesticide products use the same level. 这些水平在不同农药之间不同，且使用水平本领域已知。 These levels are different between different pesticides, and the use levels known in the art. 但是，由于所述共聚物的协同效应，所以适宜较少的使用水平。 However, due to the synergistic effect of the copolymer, it is appropriate to use fewer levels.

[0175]与单独使用等量的所选农药相比，本发明的组合物和方法提供更高的农药效果。 [0175] Compared with the same amount of selected pesticides alone, the compositions and methods of the present invention provides a higher effect of pesticides. 这种提高优选是至少约3倍高的效果，更优选是四倍高的效果。 This increase is preferably at least about 3-fold higher effect, and more preferably four times higher effect.

[0176] 下述实施例阐述了本发明优选的组合物和其农药用途。 Example [0176] The following describes the preferred composition of the invention and their use of pesticides. 然而应理解，这些实施例是阐述性的，其所含的任何内容都不应视作对本发明整体范围的限制。 However, it should be understood that these examples are illustrative, and any content contained therein should be construed as limiting the overall scope of the invention.

[0177] 实施例1 [0177] Example 1

[0178] 在本实施例中测试了不同稀释水平和含有或不含有优选共聚物的一系列市售的杀虫剂，所述共聚物为前述AVAIL®共聚物（马来酸酐/衣康酸共聚物饱和钠盐在水中的40% -60%w/w水性组合物）。 [0178] tested different levels of dilution and pesticides or may not contain a series of commercially available copolymer is preferably in the present embodiment, the copolymer is a copolymer of the aforementioned AVAIL® (maleic anhydride / itaconic acid copolymer They were washed with saturated sodium salt in water 40% -60% w / w aqueous compositions). 每组测试运行中，用火焰蚁群体测试所选的杀虫剂，测量杀死整个群体所需的时间。 Each test run, the test flame ant colony selected pesticides, measuring kill time required for the entire group. 如上所述，所述共聚物的存在产生不同的佐剂效果且显著的提高了所述杀虫剂的威力。 As described above, the presence of the copolymer produce different adjuvant effect and significantly increased the power of the insecticide.

[0179] 具体地，各测试运行中在玻璃瓶罐中加入20ml相应液体杀虫剂组合物并围着其内底部旋转。 [0179] Specifically, each of the corresponding test run was added 20ml liquid insecticide composition of glass containers and rotate around its inner bottom. 然后倒出所述液体，使剩余物在罐内表面上干燥，产生基本单体的干燥层。 Then pour the liquid, so that the residue was dried on the surface of the tank, resulting in dry layer basic monomer. 用滑石涂覆所述罐外颈表面，且所述罐的开口端放入火焰蚁巢。 Talc coated outer surface of the neck of the tank, and the open end of the canister into the flame nest. 所述滑石涂层阻止好斗的火焰蚁爬到所述罐的外表面。 Said talc coating prevents aggressive fire ants climb the outer surface of the tank. 因此火焰蚁种群建立在各罐中，然后用有孔玻璃罐盖给所述罐加盖。 Fire ant populations thus established in the tank, and then use a glass lid with holes to affix the canister. 记录所有火焰蚁致命时间。 Record all fatal fire ant time.

[0180] 在各情况中，制备杀虫剂的推荐浓度（记录为"IX"），随后用水稀释以产生稀释的组合物。 [0180] In each case, the recommended concentration for preparing pesticides (recorded as "IX"), then diluted with water to produce a diluted composition. 使用共聚物时，以30ml/加仑的水平加入所述共聚物并温和搅拌。 When a copolymer is used, in order to 30ml / gallon level of the copolymer is added with gentle stirring. 若需要，可使用较低量的共聚物，如20ml/加仑。 If necessary, the use of lower amounts of copolymers, such as 20ml / gallon.

[0181] 下述表格显示这些测试的结果。 [0181] The following table shows the results of these tests.

[0182] 表1 [0182] Table 1

[0183] [0183]

[0184] 表1的数据清晰的给出了所述共聚物对所测杀虫剂的佐剂效果。 Data [0184] Table 1 clearly shows the adjuvant effect of the copolymer measured insecticides. 在所有情况中， 杀虫剂的最低有效水平的致命时间由于存在所述共聚物而大大降低。 In all cases, the minimum effective level of pesticide lethal time due to the presence of the copolymer greatly reduced. 尽管不完全了解这种效果的机制，但是可以认为具有两性或阳性电荷的所测杀虫剂被所述共聚物修饰而改变其膜电位，如所述共聚物聚集所述电荷，从而使所述杀虫剂/共聚物混合物更有效。 Although not fully understand the mechanism of this effect, it is believed that the positively charged amphoteric or pesticides measured with the copolymer being modified to change their membrane potential, such as the copolymer of the charge accumulation, so that the insecticides / copolymer mixture more efficiently. 这通过使用具有阴性电荷的杀虫剂（Diazinon®)的一系列测试得以证实，其中与所述杀虫剂自身相比，所述共聚物没有降低致命时间。 Pesticides (Diazinon®) which has a negative charge by using a series of tests were confirmed, and wherein the pesticide compared to itself, the copolymer is not decreased time fatal.

[0185] 实施例2 [0185] Example 2

[0186] 在另一系列测试中，用具有不同比例的马来酸酐和衣康酸组分的各种共聚物与杀虫剂在不同PH水平进行测试。 [0186] In another series of tests, with maleic anhydride and itaconic acid components of various copolymers with pesticides have different proportions at different PH levels tested. 具体地，相应共聚物组合物由聚马来酸、1 : 3重量比的马来酸酐和衣康酸、I: 1重量比的马来酸酐和衣康酸、3 : 1重量比的马来酸酐和衣康酸、7 : 1 重量比的马来酸酐和衣康酸所制备。 In particular, the corresponding copolymer composition consists of polymaleic acid, 1: 3 ratio by weight of maleic anhydride and itaconic acid, I: 1 weight ratio of maleic anhydride and itaconic acid, 3: 1 weight ratio of maleic anhydride and itaconic acid, 7: 1 weight ratio of maleic anhydride and itaconic acid prepared. 然后用氢氧化钠对这些共聚物各自的单独部分进行PH 调节，以为各共聚物提供具有pH未调节的部分以及pH调节为6、7和8的部分。 With sodium hydroxide respective separate portions of these copolymers PH regulator, provided that each copolymer portion having pH unadjusted and adjusted to pH 6, 7 and 8 of the part. 然后以每加仑杀虫剂30ml共聚物的水平将这些经pH调节的测试共聚物与1/100X稀释的马拉硫磷混合。 Then 30ml per gallon pesticide levels copolymers copolymers of these tests the pH-adjusted mixed with 1 / 100X diluted malathion. 相似地，然后也以每加仑杀虫剂30ml共聚物的水平将相同的经pH调节的共聚物与1/20X水稀释的氯菊酯混合。 Similarly, and also insecticides 30ml per gallon copolymer same level of pH adjusted copolymer 1 / 20X dilution water mixing permethrin.

[0187] 然后将所述测试产物用于实施例1中相同的火焰蚁杀死实验，产生表2和表3的数据。 [0187] The test product was then used in Example 1 in the same test a flame kill ants embodiment, generates data in Table 2 and Table 3.

[0188] 表2 [0188] Table 2

[0193] 表2和3的数据证明优选的共聚物在较宽范围的不同马来酸酐/衣康酸比例都有用，且所述共聚物在较宽的PH范围中同样有效。 Data [0193] Tables 2 and 3 demonstrate preferred copolymers in a wide range of different maleic anhydride / itaconic acid ratio are used, and the copolymer in a wide range of PH equally effective.

[0194] 实施例3 [0194] Example 3

[0195] 在此实施例中，用草甘膦除草剂测试本发明共聚物的有效性。 [0195] In this embodiment, the use of glyphosate herbicide to test the effectiveness of the present invention copolymer. 用爱荷华州地区具有高约18英尺的混合雀麦草和野茅的准备种植玉米的田地作为测试地。 With Iowa region has a height of about 18 feet of Brome and wild mix of Mao fields ready for planting corn as a test ground. 为了种植，其需要杀死杂草。 In order to grow, the need to kill weeds. 已知仅用一种草甘膦应用很难有效杀灭。 Known only glyphosate application difficult to effectively kill.

[0196] 本测试中，2夸脱标准市售草甘膦与40加仑28%氮液体肥料混合，所述肥料由1/3 重量的尿素、1/3重量的硝酸铵和1/3重量的水组成。 [0196] In this test, two quarts standard commercial glyphosate was mixed with 40 gallons of 28% nitrogen liquid fertilizer, the fertilizer by a third of the weight of urea, 1/3 and 1/3 by weight by weight of ammonium nitrate of water. 作为对比，2夸脱40%重量的固体马来酸酐/衣康酸共聚物（专业肥料产品有限公司销售的用于液体的Nutrisphere_，马来酸-衣康酸共聚物钙盐，30% -60%w/w水溶液，pH1. 5)加入单独量的所述草甘膦补充肥料中。 As a comparison, two quarts of 40% by weight of solid maleic anhydride / itaconic acid copolymer (specialty fertilizer products sold Nutrisphere_ Limited for the liquid, maleic acid - itaconic acid copolymer calcium, 30% -60 % w / w aqueous solution, pH1. 5) added to the individual an amount of supplementary fertilizer glyphosate.

[0197] 以10加仑/英亩的比例将两种测试组合物喷洒在所述田地的临近测试区。 [0197] In 10 gallons / acre ratio will be two test composition sprayed on the field near the test area. 10天后，喷洒所述草甘膦和共聚物-补充的肥料的区域的草基本上完全杀灭。 After 10 days, the spraying of glyphosate and copolymers - grass fertilizer supplement region substantially complete kill. 对于不含共聚物的草甘膦-补充的肥料，需要第二次草甘膦喷洒应用才能完全杀灭。 For copolymers containing no glyphosate - supplementary fertilizer needs a second spray application of glyphosate to completely kill.

[0198] 因此，本发明的共聚物使种植提前且降低草甘膦消耗。 [0198] Accordingly, the copolymer of the present invention enables planting in advance and reduce the consumption of glyphosate.